Kinetics of the reaction of ozone with 2,4,6-trichlorophenol

The kinetics of the aqueous phase reaction between ozone and 2,4,6-trichlorophenol was studied in this work using a wetted-sphere absorber. Ozone absorption rates into an aqueous solution of trichlorophenol were interpreted to give an expression for the second-order kinetic rate constant as k 2 = 8....

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Bibliographic Details
Published in:Journal of hazardous materials 1995-04, Vol.41 (1), p.65-72
Main Authors: Davis, Richard A., Rinker, Robert G., Sandall, Orville C.
Format: Article
Language:English
Subjects:
Applied sciences
Exact sciences and technology
Freshwater
General purification processes
Pollution
Wastewaters
Water treatment and pollution
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Summary:The kinetics of the aqueous phase reaction between ozone and 2,4,6-trichlorophenol was studied in this work using a wetted-sphere absorber. Ozone absorption rates into an aqueous solution of trichlorophenol were interpreted to give an expression for the second-order kinetic rate constant as k 2 = 8.19 × 10 21 exp(−11630/ T) l/g mol s. Stoichiometry experiments showed that one mole of ozone reacts with one mole of 2,4,6-trichlorophenol.
ISSN:0304-3894
1873-3336
DOI:10.1016/0304-3894(94)00100-U