Changes in the chemistry of lakes and precipitation in high-elevation national parks in the western United States, 1985-1999

• Published in: Water resources research 2003-06, Vol.39 (6), p.n/a
• Main Authors: Clow, David W., Sickman, James O., Striegl, Robert G., Krabbenhoft, David P., Elliott, John G., Dornblaser, Mark, Roth, David A., Campbell, Donald H.
• Format: Article
• Language: English
• Subjects: alpine; atmospheric deposition; emissions; Freshwater; lake chemistry; monitoring; talus; USA, western
• ISSN: 0043-1397; 1944-7973
• DOI: 10.1029/2002WR001533

High‐elevation lakes in the western United States are sensitive to atmospheric deposition of sulfur and nitrogen due to fast hydrologic flushing rates, short growing seasons, an abundance of exposed bedrock, and a lack of well‐developed soils. This sensitivity is reflected in the dilute chemistry of the lakes, which was documented in the U.S. Environmental Protection Agency's Western Lake Survey of 1985. Sixty‐nine lakes in seven national parks sampled during the 1985 survey were resampled during fall 1999 to investigate possible decadal‐scale changes in lake chemistry. In most lakes, SO4 concentrations were slightly lower in 1999 than in 1985, consistent with a regional decrease in precipitation SO4 concentrations and in SO2 emissions in the western United States. Nitrate concentrations also tended to be slightly lower in 1999 than in 1985, in contrast with generally stable or increasing inorganic N deposition in the west. Differences in alkalinity were variable among parks but were relatively consistent within each park. Possible effects of annual and seasonal‐scale variations in precipitation amount on lake chemistry were evaluated based on climate data available for the parks and an analysis of climatic effects at two research watersheds with long‐term records. Results suggest that rain prior to sampling in 1985 may have caused elevated NO3 in some lakes due to direct runoff of precipitation and flushing of NO3 from alpine soils, which may explain some of the decrease in NO3 concentrations observed in survey lakes.