Tuning the electronic effects of aromatic phosphorus heterocycles: an unprecedented phosphinine with significant P(π)-donor properties

A hitherto unprecedented electronic situation has been observed for a substituted, pyridyl-functionalized phosphinine. In contrast to previous studies, this compound shows considerable π-donor properties as the result of the rather strong +M effect of the CH3S-substituent, changing the electronic pr...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2014-08, Vol.50 (64), p.8842-8844
Main Authors: Loibl, Antonia, de Krom, Iris, Pidko, Evgeny A, Weber, Manuela, Wiecko, Jelena, Müller, Christian
Format: Article
Language:English
Subjects:
Aromatic compounds
Electronic properties
Electronics
Phosphorus
Tuning
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Summary:A hitherto unprecedented electronic situation has been observed for a substituted, pyridyl-functionalized phosphinine. In contrast to previous studies, this compound shows considerable π-donor properties as the result of the rather strong +M effect of the CH3S-substituent, changing the electronic properties of this low-coordinate and aromatic phosphorus heterocycle substantially.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc03469d