(Ionic liquid)-derived morphology control of Nb sub(2)O sub(5) materials and their photocatalytic properties

Pseudo-hexagonal TT phase Nb sub(2)O sub(5) with various uniform crystalline morphologies such as nanorods, fibers, flower-like clusters, bundles, and porous spheres are fabricated using a hydrothermal synthesis route with ionic liquids as guiding agents. Among these morphologies, nanorods, flower-l...

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Bibliographic Details
Published in:CrystEngComm 2014-09, Vol.16 (38), p.9096-9103
Main Authors: Du, Lei, Long, Zhouyang, Wen, Haimeng, Ge, Weilin, Zhou, Yu, Wang, Jun
Format: Article
Language:English
Subjects:
Bundles
Clusters
Crystal structure
Fibers
Ionic liquids
Morphology
Nanorods
Photocatalysis
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Summary:Pseudo-hexagonal TT phase Nb sub(2)O sub(5) with various uniform crystalline morphologies such as nanorods, fibers, flower-like clusters, bundles, and porous spheres are fabricated using a hydrothermal synthesis route with ionic liquids as guiding agents. Among these morphologies, nanorods, flower-like clusters and bundles are firstly observed for Nb sub(2)O sub(5). The morphology control is easily achieved by variation of the ionic liquid concentration. A primary mechanism study indicates a similar variation regulation for morphologies of Nb sub(2)O sub(5) from rods to fibers and then spheres, when the ionic liquid concentration increases independent of the kind of ionic liquids. The photocatalytic activities of the obtained Nb sub(2)O sub(5) with various morphologies are evaluated using the photodegradation of methylene blue. The results indicate that the catalytic performance depends on the morphology, and nanorods, fibers and clusters show superior activities even in a concentrated methylene blue solution. This study develops a facile way to control the crystalline morphology of Nb sub(2)O sub(5) over a wide range and provides efficient photocatalysts using morphology control.
ISSN:1466-8033
DOI:10.1039/c4ce00987h