A Facile and General Approach to 3‑((Trifluoro­methyl)­thio)‑4H‑chromen-4-one

A facile and efficient synthetic strategy to 3-((trifluoro­methyl)­thio)-4H-chromen-4-one was developed. AgSCF3 and trichloro­iso­cyanuric acid were employed here to generate active electrophilic trifluoromethylthio species in situ. This reaction could proceed under mild conditions in a short reacti...

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Published in:Organic letters 2014-11, Vol.16 (21), p.5686-5689
Main Authors: Xiang, Haoyue, Yang, Chunhao
Format: Article
Language:English
Subjects:
Catalysis
Chromones - chemical synthesis
Chromones - chemistry
Hydrocarbons, Halogenated - chemistry
Molecular Structure
Silver - chemistry
Triazines - chemistry
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container_title Organic letters
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creator Xiang, Haoyue
Yang, Chunhao
description A facile and efficient synthetic strategy to 3-((trifluoro­methyl)­thio)-4H-chromen-4-one was developed. AgSCF3 and trichloro­iso­cyanuric acid were employed here to generate active electrophilic trifluoromethylthio species in situ. This reaction could proceed under mild conditions in a short reaction time and be insensitive to air and moisture.
doi_str_mv 10.1021/ol502751k
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source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Catalysis
Chromones - chemical synthesis
Chromones - chemistry
Hydrocarbons, Halogenated - chemistry
Molecular Structure
Silver - chemistry
Triazines - chemistry
title A Facile and General Approach to 3‑((Trifluoro­methyl)­thio)‑4H‑chromen-4-one
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