Method for Distinctive Estimation of Stored Acidity Forms in Acid Mine Wastes

• Published in: Environmental science & technology 2014-10, Vol.48 (19), p.11445-11452
• Main Authors: Li, Jun, Kawashima, Nobuyuki, Fan, Rong, Schumann, Russell C, Gerson, Andrea R, Smart, Roger St.C
• Format: Article
• Language: English
• Subjects: Acid mine drainage; Acidity; Acids; Acids - analysis; Applied sciences; Biological and physicochemical phenomena; Earth sciences; Earth, ocean, space; Engineering and environment geology. Geothermics; Environmental Monitoring - methods; Exact sciences and technology; Ferric Compounds - chemistry; Hydrolysis; Iron - chemistry; Iron Compounds - isolation & purification; Leaching; Metallurgy; Mineralogy; Minerals; Minerals - analysis; Mining; Natural water pollution; Other industrial wastes. Sewage sludge; Oxalates - chemistry; Oxidation; Pollution; Pollution, environment geology; Protons; Sulfates - analysis; Sulfates - chemistry; Sulfides - analysis; Sulfides - chemistry; Waste Products - analysis; Wastes; Water; Water treatment and pollution
• ISSN: 0013-936X; 1520-5851
• DOI: 10.1021/es502482m

Jarosites and schwertmannite can be formed in the unsaturated oxidation zone of sulfide-containing mine waste rock and tailings together with ferrihydrite and goethite. They are also widely found in process wastes from electrometallurgical smelting and metal bioleaching and within drained coastal lowland soils (acid-sulfate soils). These secondary minerals can temporarily store acidity and metals or remove and immobilize contaminants through adsorption, coprecipitation, or structural incorporation, but release both acidity and toxic metals at pH above about 4. Therefore, they have significant relevance to environmental mineralogy through their role in controlling pollutant concentrations and dynamics in contaminated aqueous environments. Most importantly, they have widely different acid release rates at different pHs and strongly affect drainage water acidity dynamics. A procedure for estimation of the amounts of these different forms of nonsulfide stored acidity in mining wastes is required in order to predict acid release rates at any pH. A four-step extraction procedure to quantify jarosite and schwertmannite separately with various soluble sulfate salts has been developed and validated. Corrections to acid potentials and estimation of acid release rates can be reliably based on this method.