Preparation and characterization of PVDF-P(PEGMA-r-MMA) ultrafiltration blend membranes via simplified blend method

• Published in: Desalination 2013-06, Vol.319, p.47-59
• Main Authors: Zhang, Ping-Yun, Xu, Zhen-Liang, Yang, Hu, Wei, Yong-Ming, Wu, Wen-Zhi, Chen, Dong-Gen
• Format: Article
• Language: English
• Subjects: Amphiphilic copolymer; Applied sciences; Blend membranes; bovine serum albumin; Chemical engineering; Coagulants; desalination; ethanol; Exact sciences and technology; Filtration; hydrophilicity; light scattering; Liquid-liquid and fluid-solid mechanical separations; Membrane separation (reverse osmosis, dialysis...); mixing; molecular weight; Organic polymers; P(PEGMA-r-MMA); Physicochemistry of polymers; Pollution; Polymerization; Preparation, kinetics, thermodynamics, mechanism and catalysts; scanning electron microscopy; Simplified blend; surface tension; ultrafiltration; viscosity
• ISSN: 0011-9164; 1873-4464
• DOI: 10.1016/j.desal.2013.04.001

P(PEGMA-r-MMA) amphiphilic copolymer with Mn of 66,500g/mol and Mw of 34,200g/mol was successfully synthesized via free radical polymerization. And polyvinylidene fluoride (PVDF)-P(PEGMA-r-MMA) blend membranes were fabricated from water and ethanol coagulants via simplified blend method by directly blending PVDF and P(PEGMA-r-MMA) amphiphilic copolymer solution (including the reaction mixture) to form casting solution. The formation of the supramolecular aggregates in PVDF solution containing the copolymer were confirmed by dynamic light scattering and scanning electron microscopy. This contributed to the micro-structure adjustment of PVDF solution and resulted in its decreasing surface tension, accelerating precipitation rate and increasing viscosity with trivial strain thinning behavior. Furthermore, the effects of the variations in dopant contents and coagulant compositions on the performances of those blend membranes were investigated. All PVDF-P(PEGMA-r-MMA) blend membranes possessed narrow distribution mean effective pore size (μ), molecular weight cut off (MWCO), improved recovery water flux after filtration experiments of bovine serum albumin and tuned configurations. Compared with the instantaneous demixing process in water coagulant, the delayed demixing process in ethanol favored the pore-forming and surface segregated of the polar head group of the copolymer, which induced the increasing μ, MWCO, tunable morphologies and hydrophilicity improvement. •Simplified blend method was beneficial to micro-stricture adjustment of PVDF casting solution.•PVDF membranes possessed narrow distribution pore size and molecular weight cut off (MWCO).•Ethanol coagulant resulted in obvious tunable morphologies and hydrophilicity improvement.