Loading…

Atmospheric Pressure Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry of Friction Modifier Additives Analyzed Directly from Base Oil Solutions

To develop new products and to apply measures of quality control quick and simple accessibility of additive composition in automotive lubrication is important. The aim of this study was to investigate the possibility of analyzing organic friction modifier additives by means of atmospheric pressure m...

Full description

Saved in:
Bibliographic Details
Published in:European journal of mass spectrometry (Chichester, England) England), 2014-01, Vol.20 (4), p.299-305
Main Authors: Widder, Lukas, Brenner, Josef, Hutter, Herbert
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c316t-316001fa1d85436fb075f26297ffc73a4d2069da082c5347bd79169c232843ff3
cites cdi_FETCH-LOGICAL-c316t-316001fa1d85436fb075f26297ffc73a4d2069da082c5347bd79169c232843ff3
container_end_page 305
container_issue 4
container_start_page 299
container_title European journal of mass spectrometry (Chichester, England)
container_volume 20
creator Widder, Lukas
Brenner, Josef
Hutter, Herbert
description To develop new products and to apply measures of quality control quick and simple accessibility of additive composition in automotive lubrication is important. The aim of this study was to investigate the possibility of analyzing organic friction modifier additives by means of atmospheric pressure matrix-assisted laser desorption/ionization mass spectrometry (AP-MALDI-MS) from lubricant solutions without the use of additional separation techniques. Analyses of selected friction modifier ethoxylated tallow amines and oleic acid amide were compared using two ionization methods, positive-ion electrospray ionization (ESI) and AP-MALDI, using a LTQ Orbitrap mass spectrometer. Pure additives were characterized from solvent solutions, as well as from synthetic and mineral base oil mixtures. Detected ions of pure additive samples consisted mainly of [M + H]+, but also alkali metal adducts [M + Na]+ and [M + K]+ could be seen. Characterizations of blends of both friction modifiers from the base oil mixtures were carried out as well and showed significant intensities for several additive peaks. Thus, this work shows a method to directly analyze friction modifier additives used in the automotive industry from an oil blend via the use of AP-MALDI without any further separation steps. The method presented will further simplify the acquisition of data on lubricant composition and additives. Furthermore, it allows the perspective of analyzing additive reaction products directly from formulated oil blends.
doi_str_mv 10.1255/ejms.1283
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1628238387</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sage_id>10.1255_ejms.1283</sage_id><sourcerecordid>1628238387</sourcerecordid><originalsourceid>FETCH-LOGICAL-c316t-316001fa1d85436fb075f26297ffc73a4d2069da082c5347bd79169c232843ff3</originalsourceid><addsrcrecordid>eNptkc1O3DAUha2qqPy0i75A5VVVFgH_JE6yDEOhSIOoBKwjT3wNHiXj1NepOrwKL4ujoazY2Efyd46lcwj5ytkJF0VxCusBk6rkB3LAy4JnqpLVx6RzVWdMqXKfHCKuGSsqVdefyL4ocsFkLg7IcxMHj-MjBNfR3wEQpwD0Wsfg_mUNosMIhi41QqDngD6M0fnN6ZXfuCc9y8Qi0tsRuhj8ADFsqbf0IsXtXr1x1iVzY4yL7i8gbTa63z6l1HMXkqvfUpuc9Cz9QW9cT299P81e_Ez2rO4RvrzeR-T-4ufd4le2vLm8WjTLrJNcxSwdjHGruamKXCq7YmVhhRJ1aW1XSp0bwVRtNKtEV8i8XJmy5qruhBRVLq2VR-THLncM_s8EGNvBYQd9rzfgJ2y5EpWQqdIyocc7tAseMYBtx-AGHbYtZ-28RTtv0c5bJPbba-y0GsC8kf_LT8D3HYD6Adq1n0JqBt9JegHukJQ7</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1628238387</pqid></control><display><type>article</type><title>Atmospheric Pressure Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry of Friction Modifier Additives Analyzed Directly from Base Oil Solutions</title><source>Sage Journals Online</source><creator>Widder, Lukas ; Brenner, Josef ; Hutter, Herbert</creator><creatorcontrib>Widder, Lukas ; Brenner, Josef ; Hutter, Herbert</creatorcontrib><description>To develop new products and to apply measures of quality control quick and simple accessibility of additive composition in automotive lubrication is important. The aim of this study was to investigate the possibility of analyzing organic friction modifier additives by means of atmospheric pressure matrix-assisted laser desorption/ionization mass spectrometry (AP-MALDI-MS) from lubricant solutions without the use of additional separation techniques. Analyses of selected friction modifier ethoxylated tallow amines and oleic acid amide were compared using two ionization methods, positive-ion electrospray ionization (ESI) and AP-MALDI, using a LTQ Orbitrap mass spectrometer. Pure additives were characterized from solvent solutions, as well as from synthetic and mineral base oil mixtures. Detected ions of pure additive samples consisted mainly of [M + H]+, but also alkali metal adducts [M + Na]+ and [M + K]+ could be seen. Characterizations of blends of both friction modifiers from the base oil mixtures were carried out as well and showed significant intensities for several additive peaks. Thus, this work shows a method to directly analyze friction modifier additives used in the automotive industry from an oil blend via the use of AP-MALDI without any further separation steps. The method presented will further simplify the acquisition of data on lubricant composition and additives. Furthermore, it allows the perspective of analyzing additive reaction products directly from formulated oil blends.</description><identifier>ISSN: 1469-0667</identifier><identifier>EISSN: 1751-6838</identifier><identifier>DOI: 10.1255/ejms.1283</identifier><identifier>PMID: 25420342</identifier><language>eng</language><publisher>London, England: SAGE Publications</publisher><ispartof>European journal of mass spectrometry (Chichester, England), 2014-01, Vol.20 (4), p.299-305</ispartof><rights>2014 Sage Publications</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-316001fa1d85436fb075f26297ffc73a4d2069da082c5347bd79169c232843ff3</citedby><cites>FETCH-LOGICAL-c316t-316001fa1d85436fb075f26297ffc73a4d2069da082c5347bd79169c232843ff3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924,79135</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/25420342$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Widder, Lukas</creatorcontrib><creatorcontrib>Brenner, Josef</creatorcontrib><creatorcontrib>Hutter, Herbert</creatorcontrib><title>Atmospheric Pressure Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry of Friction Modifier Additives Analyzed Directly from Base Oil Solutions</title><title>European journal of mass spectrometry (Chichester, England)</title><addtitle>Eur J Mass Spectrom (Chichester)</addtitle><description>To develop new products and to apply measures of quality control quick and simple accessibility of additive composition in automotive lubrication is important. The aim of this study was to investigate the possibility of analyzing organic friction modifier additives by means of atmospheric pressure matrix-assisted laser desorption/ionization mass spectrometry (AP-MALDI-MS) from lubricant solutions without the use of additional separation techniques. Analyses of selected friction modifier ethoxylated tallow amines and oleic acid amide were compared using two ionization methods, positive-ion electrospray ionization (ESI) and AP-MALDI, using a LTQ Orbitrap mass spectrometer. Pure additives were characterized from solvent solutions, as well as from synthetic and mineral base oil mixtures. Detected ions of pure additive samples consisted mainly of [M + H]+, but also alkali metal adducts [M + Na]+ and [M + K]+ could be seen. Characterizations of blends of both friction modifiers from the base oil mixtures were carried out as well and showed significant intensities for several additive peaks. Thus, this work shows a method to directly analyze friction modifier additives used in the automotive industry from an oil blend via the use of AP-MALDI without any further separation steps. The method presented will further simplify the acquisition of data on lubricant composition and additives. Furthermore, it allows the perspective of analyzing additive reaction products directly from formulated oil blends.</description><issn>1469-0667</issn><issn>1751-6838</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNptkc1O3DAUha2qqPy0i75A5VVVFgH_JE6yDEOhSIOoBKwjT3wNHiXj1NepOrwKL4ujoazY2Efyd46lcwj5ytkJF0VxCusBk6rkB3LAy4JnqpLVx6RzVWdMqXKfHCKuGSsqVdefyL4ocsFkLg7IcxMHj-MjBNfR3wEQpwD0Wsfg_mUNosMIhi41QqDngD6M0fnN6ZXfuCc9y8Qi0tsRuhj8ADFsqbf0IsXtXr1x1iVzY4yL7i8gbTa63z6l1HMXkqvfUpuc9Cz9QW9cT299P81e_Ez2rO4RvrzeR-T-4ufd4le2vLm8WjTLrJNcxSwdjHGruamKXCq7YmVhhRJ1aW1XSp0bwVRtNKtEV8i8XJmy5qruhBRVLq2VR-THLncM_s8EGNvBYQd9rzfgJ2y5EpWQqdIyocc7tAseMYBtx-AGHbYtZ-28RTtv0c5bJPbba-y0GsC8kf_LT8D3HYD6Adq1n0JqBt9JegHukJQ7</recordid><startdate>20140101</startdate><enddate>20140101</enddate><creator>Widder, Lukas</creator><creator>Brenner, Josef</creator><creator>Hutter, Herbert</creator><general>SAGE Publications</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20140101</creationdate><title>Atmospheric Pressure Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry of Friction Modifier Additives Analyzed Directly from Base Oil Solutions</title><author>Widder, Lukas ; Brenner, Josef ; Hutter, Herbert</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-316001fa1d85436fb075f26297ffc73a4d2069da082c5347bd79169c232843ff3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Widder, Lukas</creatorcontrib><creatorcontrib>Brenner, Josef</creatorcontrib><creatorcontrib>Hutter, Herbert</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>European journal of mass spectrometry (Chichester, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Widder, Lukas</au><au>Brenner, Josef</au><au>Hutter, Herbert</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Atmospheric Pressure Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry of Friction Modifier Additives Analyzed Directly from Base Oil Solutions</atitle><jtitle>European journal of mass spectrometry (Chichester, England)</jtitle><addtitle>Eur J Mass Spectrom (Chichester)</addtitle><date>2014-01-01</date><risdate>2014</risdate><volume>20</volume><issue>4</issue><spage>299</spage><epage>305</epage><pages>299-305</pages><issn>1469-0667</issn><eissn>1751-6838</eissn><abstract>To develop new products and to apply measures of quality control quick and simple accessibility of additive composition in automotive lubrication is important. The aim of this study was to investigate the possibility of analyzing organic friction modifier additives by means of atmospheric pressure matrix-assisted laser desorption/ionization mass spectrometry (AP-MALDI-MS) from lubricant solutions without the use of additional separation techniques. Analyses of selected friction modifier ethoxylated tallow amines and oleic acid amide were compared using two ionization methods, positive-ion electrospray ionization (ESI) and AP-MALDI, using a LTQ Orbitrap mass spectrometer. Pure additives were characterized from solvent solutions, as well as from synthetic and mineral base oil mixtures. Detected ions of pure additive samples consisted mainly of [M + H]+, but also alkali metal adducts [M + Na]+ and [M + K]+ could be seen. Characterizations of blends of both friction modifiers from the base oil mixtures were carried out as well and showed significant intensities for several additive peaks. Thus, this work shows a method to directly analyze friction modifier additives used in the automotive industry from an oil blend via the use of AP-MALDI without any further separation steps. The method presented will further simplify the acquisition of data on lubricant composition and additives. Furthermore, it allows the perspective of analyzing additive reaction products directly from formulated oil blends.</abstract><cop>London, England</cop><pub>SAGE Publications</pub><pmid>25420342</pmid><doi>10.1255/ejms.1283</doi><tpages>7</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1469-0667
ispartof European journal of mass spectrometry (Chichester, England), 2014-01, Vol.20 (4), p.299-305
issn 1469-0667
1751-6838
language eng
recordid cdi_proquest_miscellaneous_1628238387
source Sage Journals Online
title Atmospheric Pressure Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry of Friction Modifier Additives Analyzed Directly from Base Oil Solutions
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-12T23%3A39%3A47IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Atmospheric%20Pressure%20Matrix-Assisted%20Laser%20Desorption/Ionization%20Mass%20Spectrometry%20of%20Friction%20Modifier%20Additives%20Analyzed%20Directly%20from%20Base%20Oil%20Solutions&rft.jtitle=European%20journal%20of%20mass%20spectrometry%20(Chichester,%20England)&rft.au=Widder,%20Lukas&rft.date=2014-01-01&rft.volume=20&rft.issue=4&rft.spage=299&rft.epage=305&rft.pages=299-305&rft.issn=1469-0667&rft.eissn=1751-6838&rft_id=info:doi/10.1255/ejms.1283&rft_dat=%3Cproquest_cross%3E1628238387%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c316t-316001fa1d85436fb075f26297ffc73a4d2069da082c5347bd79169c232843ff3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1628238387&rft_id=info:pmid/25420342&rft_sage_id=10.1255_ejms.1283&rfr_iscdi=true