Porous organic ligands (POLs) for synthesizing highly efficient heterogeneous catalysts

We reported a universal route for synthesizing porous organic ligands (POLs) via solvothermal polymerization. The POLs were obtained quantitatively, showing high surface area, large pore volume, hierarchical porosity, and superior stability. The POL bearing a triphenylphosphine supported rhodium cat...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2014-10, Vol.50 (80), p.11844-11847
Main Authors: Sun, Qi, Jiang, Miao, Shen, Zhenju, Jin, Yinying, Pan, Shuxiang, Wang, Liang, Meng, Xiangju, Chen, Wangzhi, Ding, Yunjie, Li, Jixue, Xiao, Feng-Shou
Format: Article
Language:English
Subjects:
Catalysis
Catalysts
Ligands
Porosity
Recyclability
Rhodium
Stability
Surface area
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Summary:We reported a universal route for synthesizing porous organic ligands (POLs) via solvothermal polymerization. The POLs were obtained quantitatively, showing high surface area, large pore volume, hierarchical porosity, and superior stability. The POL bearing a triphenylphosphine supported rhodium catalyst (Rh/POL-PPh3) exhibits high activity and excellent recyclability in 1-octene hydroformylation.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc03884c