The benzoyl peroxide-promoted functionalization of simple alkanes with 2-aryl phenyl isonitrile

The benzoyl peroxide (BPO)-promoted phenanthridinylation of simple alkanes with isonitrile is developed via C(sp(3))-H and C(sp(2))-H bond cleavage. This procedure is featured by dual C-C bond formation proceeding with the addition of an alkyl radical to isonitrile followed by radical aromatic cycli...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2014-08, Vol.50 (65), p.9179-9181
Main Authors: Sha, Wanxing, Yu, Jin-Tao, Jiang, Yan, Yang, Haitao, Cheng, Jiang
Format: Article
Language:English
Subjects:
Alkanes
Benzoyl peroxide
Bonding
Carbon-carbon composites
Cleavage
Phenyls
Radicals
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Summary:The benzoyl peroxide (BPO)-promoted phenanthridinylation of simple alkanes with isonitrile is developed via C(sp(3))-H and C(sp(2))-H bond cleavage. This procedure is featured by dual C-C bond formation proceeding with the addition of an alkyl radical to isonitrile followed by radical aromatic cyclization.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc03304c