Effects of silicon and thermo-mechanical process on microstructure and properties of Cu–10Ni–3Al–0.8Si alloy

• Published in: Materials in engineering 2014-10, Vol.62, p.265-270
• Main Authors: Shen, Leinuo, Li, Zhou, Zhang, Zheming, Dong, Qiyi, Xiao, Zhu, Lei, Qian, Qiu, Wenting
• Format: Article
• Language: English
• Subjects: AGING MECHANISMS; Cold rolling; COPPER ALLOYS (40 TO 99.3 CU); Copper base alloys; ELECTRICAL CONDUCTIVITY; Electrical resistivity; Intermetallic compounds; Intermetallics; Microstructure; MICROSTRUCTURES; Nickel aluminides; Orientation relationship; Precipitation; Resistivity; ROLLING; Strength; TENSILE STRENGTH; Thermomechanical treatment; YIELD STRENGTH
• ISSN: 0261-3069
• DOI: 10.1016/j.matdes.2014.04.053

•Cu–10Ni–3Al–0.8Si alloy with ultra-high strength was designed.•The addition of silicon hindered the precipitation of large NiAl phase.•Tensile strength and electrical conductivity were 1180MPa and 18.1% IACS.•Nano-scale Ni2Si and Ni3Al improved the strength and electrical conductivity. Cu–10Ni–3Al–0.8Si alloy with ultra-high strength was designed and its microstructure was studied using optical microscopy, scanning electron microscopy, transmission electron microscopy. The alloy went through a set of thermo-mechanical process: solution treated at 950°C for 4h, then cold-rolled by 50% and aged at 450°C for 8h, followed by 60% cold-rolling and aging at 450°C for 8h. After these treatment, the tensile strength was 1180MPa, yield strength was 1133MPa and electrical conductivity was 18.1% IACS, respectively. The comprehensive properties, especially the electrical conductivity of the designed alloy, were much higher than those of traditional Cu–Ni–Al alloys. The addition of silicon in the designed alloy hindered the precipitation of large-scale NiAl phase and improved the strength of the alloy. The orientation relationships between δ-Ni2Si, Ni3Al precipitates and copper matrix were: [001]Cu‖[001]Ni3Al‖[001]δ,(110)Cu‖(110)Ni3Al‖(010)δ,(11¯0)Cu‖(11¯0)Ni3Al||(100)δ, respectively.