Droplet evaporation on a substrate at the final stage of Low Pressure Spray Pyrolysis and the final morphology of nanoparticles

For lowered pressure conditions femtoliter droplets evaporation on metallic substrate is investigated by experimental and theoretical methods. Simulation results of the kinetics of droplet evaporation, which substantially used the pinning effect, are presented. It was shown that the evaporation time...

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Bibliographic Details
Published in:International journal of heat and mass transfer 2014-11, Vol.78, p.599-603
Main Authors: Fisenko, S.P., Khodyko, Yu.A., Penyazkov, O.G., Saverchenko, V.I.
Format: Article
Language:English
Subjects:
Aqueous solutions
Deposition
Droplets
Evaporation
Free molecular regime
Low pressure
Nanoparticles
Pinning effect
Shells
Spray pyrolysis
Supersaturated solution
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Summary:For lowered pressure conditions femtoliter droplets evaporation on metallic substrate is investigated by experimental and theoretical methods. Simulation results of the kinetics of droplet evaporation, which substantially used the pinning effect, are presented. It was shown that the evaporation time of a droplet with the height 5μm is about 0.01s. For evaporation on the substrate droplets of aqueous solution with nanoparticles inside it was predicted the formation of the core–shell structure of nanoparticles. Qualitative confirmation of this effect is obtained. For Low-Pressure Spray Pyrolysis of droplets of aqueous solution of salts, the core is a metal oxide and the shell is a deposited layer of the initial salt.
ISSN:0017-9310
1879-2189
DOI:10.1016/j.ijheatmasstransfer.2014.07.049