Creep deformation-induced antiphase boundaries in L12-containing single-crystal cobalt-base superalloys

• Published in: Acta materialia 2014-09, Vol.77, p.352-359
• Main Authors: Eggeler, Yolita M., Titus, Michael S., Suzuki, Akane, Pollock, Tresa M.
• Format: Article
• Language: English
• Subjects: Antiphase boundaries; Antiphase boundary; Applied sciences; Burgers vector; Cobalt alloys; Creep; Creep (materials); Dislocations; Exact sciences and technology; High-temperature creep; Intermetallic compounds; Mechanical properties and methods of testing. Rheology. Fracture mechanics. Tribology; Metals. Metallurgy; Precipitates; Precipitation; Single crystals; Superalloys; Transmission electron microscopy
• ISSN: 1359-6454; 1873-2453
• DOI: 10.1016/j.actamat.2014.04.037

Creep-induced antiphase boundaries (APBs) in new Co-base single-crystal superalloys with coherent embedded L12-γ′ precipitates have been observed. APBs formed during single-crystal tensile creep tests performed at 900°C under vacuum at stresses between 275 and 310MPa. The alloys investigated contained 30–39at.% Ni, which was added to the Co–Al–W ternary system to expand the γ–γ′ phase field and increase the γ′-solvus. Transmission electron microscopy (TEM) using two-beam conditions with fundamental and superlattice reflections was performed for defect characterization. The Burgers vector b of dislocations associated with the APBs was determined to be of type b=a0/2[011] and a0/2[011¯]. The displacement vectors, R, of the APBs matched the dislocation Burgers vectors, with R=b=a0/2[011]. APBs were observed in nearly every precipitate beyond 0.5% creep strain for the compositions investigated. The implications for high-temperature properties are discussed.