Effect of silica nanoparticles on the stability of decontamination foam and their application for oxide dissolution of corroded specimens

• Published in: Annals of nuclear energy 2014-11, Vol.73, p.168-174
• Main Authors: Yoon, In-Ho, Jung, Chong-Hun, Yoon, Suk Bon, Park, Sang Yoon, Moon, Jei-Kwon, Choi, Wang-Kyu
• Format: Article
• Language: English
• Subjects: Decontamination; Decontamination foam; Dissolution; Foam stability; Foams; Nanoparticles; Non-ionic surfactant; Oxide dissolution; Oxides; Silica nanoparticles; Silicon dioxide; Stability; Surfactants; Viscosifier
• ISSN: 0306-4549; 1873-2100
• DOI: 10.1016/j.anucene.2014.06.046

•This study investigated the effect of stabilizers for decontamination foam.•Silica nanoparticles played an important role for foam stability in acidic pH.•The increase in foam stability enhanced the decontamination efficiency. Foam stability was investigated by varying the amount of silica nanoparticles in a decontamination foam containing a surfactant and a stabilizer. In addition, a study on the oxide dissolution of a corroded specimen using a decontamination foam was performed to evaluate the decontamination efficiency of the foam. The decontamination foam prepared with Elotant™ Milcoside 440N (EM440N) as a non-ionic surfactant displayed the highest foam stability compared with that of foam containing other surfactants such as SDS and Triton X-100 in acidic pH. For the decontamination foam prepared using silica nanoparticles, the liquid volume in the foam was enhanced by a factor of 2 compared with that of the foam prepared using only a surfactant. Silica nanoparticles are thought to play a key role as an effective stabilizer of decontamination foam in acidic pH. The decontamination efficiency toward dissolving iron was improved by up to approximately 94% when using a decontamination foam in 1.0% EM440N consisting of the mixture of 3.0wt.% silica nanoparticles and 0.1wt.% xanthan gum compared with that of the chemical decontamination agent alone. This result indicates that an increase in foam stability enhanced the oxide dissolution of the decontamination foam owing to an increase in the contact time between the decontaminant foam and the corroded specimen.