Bestowing structure upon the pores of a supramolecular network

Trigonal molecules compartmentalise the pores of a honeycomb network of 3,4:9,10-tetracarboxylic diimide (PTCDI) and 1,3,5-triazine-2,4,6-triamine (melamine). Extending the 1,3,5-tri(phenylene-ethynylene)benzene core by a phenyl group allows for a well-defined accommodation of the molecule into two...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2014-11, Vol.50 (91), p.14175-14178
Main Authors: Karamzadeh, Baharan, Eaton, Thomas, Cebula, Izabela, Torres, David Muñoz, Neuburger, Markus, Mayor, Marcel, Buck, Manfred
Format: Article
Language:English
Subjects:
Accommodation
Derivatives
Diimide
Equivalence
Honeycomb
Melamine
Networks
Porosity
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Summary:Trigonal molecules compartmentalise the pores of a honeycomb network of 3,4:9,10-tetracarboxylic diimide (PTCDI) and 1,3,5-triazine-2,4,6-triamine (melamine). Extending the 1,3,5-tri(phenylene-ethynylene)benzene core by a phenyl group allows for a well-defined accommodation of the molecule into two symmetry equivalent positions in the pore. The corresponding styryl or phenylene-ethynylene derivatives exceed the pore size and, thus, impede pore modification.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc05934d