Loading…
Synthesis and Properties of Salicyladehyde Salicyhydrazone Derivatives and Their Europium Complexes
Four novel salicyladehyde salicyhydrazone derivatives and their corresponding europium (Eu 3+ ) complexes were synthesized and characterized. The formulas of the complexes were [EuL a−d (NO 3 ) 2 ](NO 3 ) · H 2 O. The investigatoin of fluoresence properties of the Eu 3+ complexes showed that the sal...
Saved in:
| Published in: | Journal of fluorescence 2014-11, Vol.24 (6), p.1661-1669 |
|---|---|
| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c447t-4baeffcd8d70d687231d76e35a86702992be6b3c945ce552ab468d02e0a76eb53 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c447t-4baeffcd8d70d687231d76e35a86702992be6b3c945ce552ab468d02e0a76eb53 |
| container_end_page | 1669 |
| container_issue | 6 |
| container_start_page | 1661 |
| container_title | Journal of fluorescence |
| container_volume | 24 |
| creator | Meng, Defen Liu, Fen Lian, Xiaomei Yang, Zehui Guo, Dongcai |
| description | Four novel salicyladehyde salicyhydrazone derivatives and their corresponding europium (Eu
3+
) complexes were synthesized and characterized. The formulas of the complexes were [EuL
a−d
(NO
3
)
2
](NO
3
) · H
2
O. The investigatoin of fluoresence properties of the Eu
3+
complexes showed that the salicyladehyde salicyhydrazone derivatives were efficient sensitizers for the fluoresence of Eu
3+
ions. The fluorescence intensity of the complex substituted by methyl (−CH
3
) was the strongest among all the Eu
3+
complexes. The exploration of the electrochemical properties of the Eu
3+
complexes showed that the introduction of electron-donating groups methyl and methoxyl (−CH
3
and −OCH
3
) could increase the oxidation potential and the highest occupied molecular orbital (HOMO) energy level of the Eu
3+
complex; however, the results of introduction of electron-withdrawing group were just opposite. |
| doi_str_mv | 10.1007/s10895-014-1453-5 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1651425063</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1651425063</sourcerecordid><originalsourceid>FETCH-LOGICAL-c447t-4baeffcd8d70d687231d76e35a86702992be6b3c945ce552ab468d02e0a76eb53</originalsourceid><addsrcrecordid>eNqNkctOwzAQRS0EoqXwAWxQlmwCY8dOnCUqT6kSSMDacuIJNcqj2ElF-XpcpbBErDy2zz2LuYScUrigANmlpyBzEQPlMeUiicUemVKRJTHPc74fZgiPICCfkCPv3wEgl1wekgkTTPKMsikpnzdtv0RvfaRbEz25boWut-ijroqedW3LTa0NLjcGd9cwOv3VtRhdo7Nr3ds1juGXJVoX3QzBYYcmmnfNqsZP9MfkoNK1x5PdOSOvtzcv8_t48Xj3ML9axCXnWR_zQmNVlUaaDEwqM5ZQk6WYCC3TDFieswLTIilzLkoUgumCp9IAQ9ABK0QyI-ejd-W6jwF9rxrrS6xr3WI3eEVTQTkTkCb_QJmUkiZya6UjWrrOe4eVWjnbaLdRFNS2BjXWoEINaluD2mbOdvqhaND8Jn72HgA2Aj58tW_o1Hs3uDZs5w_rN-Hqk9g</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1628881385</pqid></control><display><type>article</type><title>Synthesis and Properties of Salicyladehyde Salicyhydrazone Derivatives and Their Europium Complexes</title><source>Springer Nature</source><creator>Meng, Defen ; Liu, Fen ; Lian, Xiaomei ; Yang, Zehui ; Guo, Dongcai</creator><creatorcontrib>Meng, Defen ; Liu, Fen ; Lian, Xiaomei ; Yang, Zehui ; Guo, Dongcai</creatorcontrib><description>Four novel salicyladehyde salicyhydrazone derivatives and their corresponding europium (Eu
3+
) complexes were synthesized and characterized. The formulas of the complexes were [EuL
a−d
(NO
3
)
2
](NO
3
) · H
2
O. The investigatoin of fluoresence properties of the Eu
3+
complexes showed that the salicyladehyde salicyhydrazone derivatives were efficient sensitizers for the fluoresence of Eu
3+
ions. The fluorescence intensity of the complex substituted by methyl (−CH
3
) was the strongest among all the Eu
3+
complexes. The exploration of the electrochemical properties of the Eu
3+
complexes showed that the introduction of electron-donating groups methyl and methoxyl (−CH
3
and −OCH
3
) could increase the oxidation potential and the highest occupied molecular orbital (HOMO) energy level of the Eu
3+
complex; however, the results of introduction of electron-withdrawing group were just opposite.</description><identifier>ISSN: 1053-0509</identifier><identifier>EISSN: 1573-4994</identifier><identifier>DOI: 10.1007/s10895-014-1453-5</identifier><identifier>PMID: 25284712</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Aldehydes - chemistry ; Analytical Chemistry ; Biochemistry ; Biological and Medical Physics ; Biomedical and Life Sciences ; Biomedicine ; Biophysics ; Biotechnology ; Derivatives ; Electrode potentials ; Energy levels ; Europium ; Europium - chemistry ; Exploration ; Fluorescence ; Hydrazones - chemistry ; Models, Molecular ; Molecular orbitals ; Molecular Structure ; Organometallic Compounds - chemical synthesis ; Original Paper ; Synthesis</subject><ispartof>Journal of fluorescence, 2014-11, Vol.24 (6), p.1661-1669</ispartof><rights>Springer Science+Business Media New York 2014</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c447t-4baeffcd8d70d687231d76e35a86702992be6b3c945ce552ab468d02e0a76eb53</citedby><cites>FETCH-LOGICAL-c447t-4baeffcd8d70d687231d76e35a86702992be6b3c945ce552ab468d02e0a76eb53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/25284712$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Meng, Defen</creatorcontrib><creatorcontrib>Liu, Fen</creatorcontrib><creatorcontrib>Lian, Xiaomei</creatorcontrib><creatorcontrib>Yang, Zehui</creatorcontrib><creatorcontrib>Guo, Dongcai</creatorcontrib><title>Synthesis and Properties of Salicyladehyde Salicyhydrazone Derivatives and Their Europium Complexes</title><title>Journal of fluorescence</title><addtitle>J Fluoresc</addtitle><addtitle>J Fluoresc</addtitle><description>Four novel salicyladehyde salicyhydrazone derivatives and their corresponding europium (Eu
3+
) complexes were synthesized and characterized. The formulas of the complexes were [EuL
a−d
(NO
3
)
2
](NO
3
) · H
2
O. The investigatoin of fluoresence properties of the Eu
3+
complexes showed that the salicyladehyde salicyhydrazone derivatives were efficient sensitizers for the fluoresence of Eu
3+
ions. The fluorescence intensity of the complex substituted by methyl (−CH
3
) was the strongest among all the Eu
3+
complexes. The exploration of the electrochemical properties of the Eu
3+
complexes showed that the introduction of electron-donating groups methyl and methoxyl (−CH
3
and −OCH
3
) could increase the oxidation potential and the highest occupied molecular orbital (HOMO) energy level of the Eu
3+
complex; however, the results of introduction of electron-withdrawing group were just opposite.</description><subject>Aldehydes - chemistry</subject><subject>Analytical Chemistry</subject><subject>Biochemistry</subject><subject>Biological and Medical Physics</subject><subject>Biomedical and Life Sciences</subject><subject>Biomedicine</subject><subject>Biophysics</subject><subject>Biotechnology</subject><subject>Derivatives</subject><subject>Electrode potentials</subject><subject>Energy levels</subject><subject>Europium</subject><subject>Europium - chemistry</subject><subject>Exploration</subject><subject>Fluorescence</subject><subject>Hydrazones - chemistry</subject><subject>Models, Molecular</subject><subject>Molecular orbitals</subject><subject>Molecular Structure</subject><subject>Organometallic Compounds - chemical synthesis</subject><subject>Original Paper</subject><subject>Synthesis</subject><issn>1053-0509</issn><issn>1573-4994</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqNkctOwzAQRS0EoqXwAWxQlmwCY8dOnCUqT6kSSMDacuIJNcqj2ElF-XpcpbBErDy2zz2LuYScUrigANmlpyBzEQPlMeUiicUemVKRJTHPc74fZgiPICCfkCPv3wEgl1wekgkTTPKMsikpnzdtv0RvfaRbEz25boWut-ijroqedW3LTa0NLjcGd9cwOv3VtRhdo7Nr3ds1juGXJVoX3QzBYYcmmnfNqsZP9MfkoNK1x5PdOSOvtzcv8_t48Xj3ML9axCXnWR_zQmNVlUaaDEwqM5ZQk6WYCC3TDFieswLTIilzLkoUgumCp9IAQ9ABK0QyI-ejd-W6jwF9rxrrS6xr3WI3eEVTQTkTkCb_QJmUkiZya6UjWrrOe4eVWjnbaLdRFNS2BjXWoEINaluD2mbOdvqhaND8Jn72HgA2Aj58tW_o1Hs3uDZs5w_rN-Hqk9g</recordid><startdate>20141101</startdate><enddate>20141101</enddate><creator>Meng, Defen</creator><creator>Liu, Fen</creator><creator>Lian, Xiaomei</creator><creator>Yang, Zehui</creator><creator>Guo, Dongcai</creator><general>Springer US</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20141101</creationdate><title>Synthesis and Properties of Salicyladehyde Salicyhydrazone Derivatives and Their Europium Complexes</title><author>Meng, Defen ; Liu, Fen ; Lian, Xiaomei ; Yang, Zehui ; Guo, Dongcai</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c447t-4baeffcd8d70d687231d76e35a86702992be6b3c945ce552ab468d02e0a76eb53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Aldehydes - chemistry</topic><topic>Analytical Chemistry</topic><topic>Biochemistry</topic><topic>Biological and Medical Physics</topic><topic>Biomedical and Life Sciences</topic><topic>Biomedicine</topic><topic>Biophysics</topic><topic>Biotechnology</topic><topic>Derivatives</topic><topic>Electrode potentials</topic><topic>Energy levels</topic><topic>Europium</topic><topic>Europium - chemistry</topic><topic>Exploration</topic><topic>Fluorescence</topic><topic>Hydrazones - chemistry</topic><topic>Models, Molecular</topic><topic>Molecular orbitals</topic><topic>Molecular Structure</topic><topic>Organometallic Compounds - chemical synthesis</topic><topic>Original Paper</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Meng, Defen</creatorcontrib><creatorcontrib>Liu, Fen</creatorcontrib><creatorcontrib>Lian, Xiaomei</creatorcontrib><creatorcontrib>Yang, Zehui</creatorcontrib><creatorcontrib>Guo, Dongcai</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of fluorescence</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Meng, Defen</au><au>Liu, Fen</au><au>Lian, Xiaomei</au><au>Yang, Zehui</au><au>Guo, Dongcai</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Properties of Salicyladehyde Salicyhydrazone Derivatives and Their Europium Complexes</atitle><jtitle>Journal of fluorescence</jtitle><stitle>J Fluoresc</stitle><addtitle>J Fluoresc</addtitle><date>2014-11-01</date><risdate>2014</risdate><volume>24</volume><issue>6</issue><spage>1661</spage><epage>1669</epage><pages>1661-1669</pages><issn>1053-0509</issn><eissn>1573-4994</eissn><abstract>Four novel salicyladehyde salicyhydrazone derivatives and their corresponding europium (Eu
3+
) complexes were synthesized and characterized. The formulas of the complexes were [EuL
a−d
(NO
3
)
2
](NO
3
) · H
2
O. The investigatoin of fluoresence properties of the Eu
3+
complexes showed that the salicyladehyde salicyhydrazone derivatives were efficient sensitizers for the fluoresence of Eu
3+
ions. The fluorescence intensity of the complex substituted by methyl (−CH
3
) was the strongest among all the Eu
3+
complexes. The exploration of the electrochemical properties of the Eu
3+
complexes showed that the introduction of electron-donating groups methyl and methoxyl (−CH
3
and −OCH
3
) could increase the oxidation potential and the highest occupied molecular orbital (HOMO) energy level of the Eu
3+
complex; however, the results of introduction of electron-withdrawing group were just opposite.</abstract><cop>Boston</cop><pub>Springer US</pub><pmid>25284712</pmid><doi>10.1007/s10895-014-1453-5</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1053-0509 |
| ispartof | Journal of fluorescence, 2014-11, Vol.24 (6), p.1661-1669 |
| issn | 1053-0509 1573-4994 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1651425063 |
| source | Springer Nature |
| subjects | Aldehydes - chemistry Analytical Chemistry Biochemistry Biological and Medical Physics Biomedical and Life Sciences Biomedicine Biophysics Biotechnology Derivatives Electrode potentials Energy levels Europium Europium - chemistry Exploration Fluorescence Hydrazones - chemistry Models, Molecular Molecular orbitals Molecular Structure Organometallic Compounds - chemical synthesis Original Paper Synthesis |
| title | Synthesis and Properties of Salicyladehyde Salicyhydrazone Derivatives and Their Europium Complexes |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T14%3A56%3A23IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20and%20Properties%20of%20Salicyladehyde%20Salicyhydrazone%20Derivatives%20and%20Their%20Europium%20Complexes&rft.jtitle=Journal%20of%20fluorescence&rft.au=Meng,%20Defen&rft.date=2014-11-01&rft.volume=24&rft.issue=6&rft.spage=1661&rft.epage=1669&rft.pages=1661-1669&rft.issn=1053-0509&rft.eissn=1573-4994&rft_id=info:doi/10.1007/s10895-014-1453-5&rft_dat=%3Cproquest_cross%3E1651425063%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c447t-4baeffcd8d70d687231d76e35a86702992be6b3c945ce552ab468d02e0a76eb53%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1628881385&rft_id=info:pmid/25284712&rfr_iscdi=true |