Synthesis of high quality alkyl naphthenic kerosene by reacting an oil refinery with a biomass refinery stream

Alkylation of aromatics with HMF is a new route for the synthesis of biofuels. Alkylation of toluene with HMF has been studied in the presence of large pore (HBeta, USY and Mordenite), delaminated zeolites as well as on mesoporous aluminosilicates. In all cases a mixture of monoalkylated products of...

Full description

Saved in:
Bibliographic Details
Published in:Energy & environmental science 2015-01, Vol.8 (1), p.317-331
Main Authors: Arias, Karen S, Climent, Maria J, Corma, Avelino, Iborra, Sara
Format: Article
Language:English
Subjects:
Alkylation
Catalysis
Catalysts
Kerosene
Porosity
Refineries
Synthesis
Titanium dioxide
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c370t-5122479bc5b00aaf8e4bef87f009f8a8fde6b1e7201f41fad1e0bc5c52df14a03
cites cdi_FETCH-LOGICAL-c370t-5122479bc5b00aaf8e4bef87f009f8a8fde6b1e7201f41fad1e0bc5c52df14a03
container_end_page 331
container_issue 1
container_start_page 317
container_title Energy & environmental science
container_volume 8
creator Arias, Karen S
Climent, Maria J
Corma, Avelino
Iborra, Sara
description Alkylation of aromatics with HMF is a new route for the synthesis of biofuels. Alkylation of toluene with HMF has been studied in the presence of large pore (HBeta, USY and Mordenite), delaminated zeolites as well as on mesoporous aluminosilicates. In all cases a mixture of monoalkylated products of 5-(o-, m- and p-methyl)benzylfuran-2-carbaldehyde and OBMF coming from self etherification of HMF were obtained. Large pore 3D (USY) and especially 2D (ITQ-2) zeolites are active and selective catalysts for this transformation. The alkylation reaction was extended successfully to other substituted benzenes as well as to a heavy reformate mixture as source aromatic compounds, achieving 91% yield of alkylated products with 93% selectivity. Further hydrodeoxygenation of alkylated compounds in a fixed bed continuous reactor was performed using Pt/C and Pt/TiO sub(2) as catalysts allowing to obtain a hydrocarbon mixture containing alkylcyclohexane compounds that can be used as high quality kerosene.
doi_str_mv 10.1039/c4ee03194f
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1651430779</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1647019674</sourcerecordid><originalsourceid>FETCH-LOGICAL-c370t-5122479bc5b00aaf8e4bef87f009f8a8fde6b1e7201f41fad1e0bc5c52df14a03</originalsourceid><addsrcrecordid>eNqNkMFOwzAMhiMEEmNw4QlyREgFp02b5oimbSBN4gCcKzdz1rA23ZpOqG9PYSCunGz_-mzJH2PXAu4EJPreSCJIhJb2hE2ESmWUKshOf_tMx-fsIoR3gCwGpSfMvwy-ryi4wFvLK7ep-P6AtesHjvV2qLnHXTUC3hm-pa4N5ImXA-8ITe_8hqPnravH2TpP3cA_XF9x5KVrGwzhLw_9uNJcsjOLdaCrnzplb4v56-wxWj0vn2YPq8gkCvooFXEslS5NWgIg2pxkSTZXFkDbHHO7pqwUpGIQVgqLa0EwwiaN11ZIhGTKbo53d127P1Doi8YFQ3WNntpDKESWCpmAUvofqFQgdKbkiN4eUTOKCONrxa5zDXZDIaD48l_M5Hz-7X-RfALNRXo9</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1647019674</pqid></control><display><type>article</type><title>Synthesis of high quality alkyl naphthenic kerosene by reacting an oil refinery with a biomass refinery stream</title><source>Royal Society of Chemistry Journals</source><creator>Arias, Karen S ; Climent, Maria J ; Corma, Avelino ; Iborra, Sara</creator><creatorcontrib>Arias, Karen S ; Climent, Maria J ; Corma, Avelino ; Iborra, Sara</creatorcontrib><description>Alkylation of aromatics with HMF is a new route for the synthesis of biofuels. Alkylation of toluene with HMF has been studied in the presence of large pore (HBeta, USY and Mordenite), delaminated zeolites as well as on mesoporous aluminosilicates. In all cases a mixture of monoalkylated products of 5-(o-, m- and p-methyl)benzylfuran-2-carbaldehyde and OBMF coming from self etherification of HMF were obtained. Large pore 3D (USY) and especially 2D (ITQ-2) zeolites are active and selective catalysts for this transformation. The alkylation reaction was extended successfully to other substituted benzenes as well as to a heavy reformate mixture as source aromatic compounds, achieving 91% yield of alkylated products with 93% selectivity. Further hydrodeoxygenation of alkylated compounds in a fixed bed continuous reactor was performed using Pt/C and Pt/TiO sub(2) as catalysts allowing to obtain a hydrocarbon mixture containing alkylcyclohexane compounds that can be used as high quality kerosene.</description><identifier>ISSN: 1754-5692</identifier><identifier>EISSN: 1754-5706</identifier><identifier>DOI: 10.1039/c4ee03194f</identifier><language>eng</language><subject>Alkylation ; Catalysis ; Catalysts ; Kerosene ; Porosity ; Refineries ; Synthesis ; Titanium dioxide</subject><ispartof>Energy &amp; environmental science, 2015-01, Vol.8 (1), p.317-331</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c370t-5122479bc5b00aaf8e4bef87f009f8a8fde6b1e7201f41fad1e0bc5c52df14a03</citedby><cites>FETCH-LOGICAL-c370t-5122479bc5b00aaf8e4bef87f009f8a8fde6b1e7201f41fad1e0bc5c52df14a03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,778,782,27907,27908</link.rule.ids></links><search><creatorcontrib>Arias, Karen S</creatorcontrib><creatorcontrib>Climent, Maria J</creatorcontrib><creatorcontrib>Corma, Avelino</creatorcontrib><creatorcontrib>Iborra, Sara</creatorcontrib><title>Synthesis of high quality alkyl naphthenic kerosene by reacting an oil refinery with a biomass refinery stream</title><title>Energy &amp; environmental science</title><description>Alkylation of aromatics with HMF is a new route for the synthesis of biofuels. Alkylation of toluene with HMF has been studied in the presence of large pore (HBeta, USY and Mordenite), delaminated zeolites as well as on mesoporous aluminosilicates. In all cases a mixture of monoalkylated products of 5-(o-, m- and p-methyl)benzylfuran-2-carbaldehyde and OBMF coming from self etherification of HMF were obtained. Large pore 3D (USY) and especially 2D (ITQ-2) zeolites are active and selective catalysts for this transformation. The alkylation reaction was extended successfully to other substituted benzenes as well as to a heavy reformate mixture as source aromatic compounds, achieving 91% yield of alkylated products with 93% selectivity. Further hydrodeoxygenation of alkylated compounds in a fixed bed continuous reactor was performed using Pt/C and Pt/TiO sub(2) as catalysts allowing to obtain a hydrocarbon mixture containing alkylcyclohexane compounds that can be used as high quality kerosene.</description><subject>Alkylation</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Kerosene</subject><subject>Porosity</subject><subject>Refineries</subject><subject>Synthesis</subject><subject>Titanium dioxide</subject><issn>1754-5692</issn><issn>1754-5706</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqNkMFOwzAMhiMEEmNw4QlyREgFp02b5oimbSBN4gCcKzdz1rA23ZpOqG9PYSCunGz_-mzJH2PXAu4EJPreSCJIhJb2hE2ESmWUKshOf_tMx-fsIoR3gCwGpSfMvwy-ryi4wFvLK7ep-P6AtesHjvV2qLnHXTUC3hm-pa4N5ImXA-8ITe_8hqPnravH2TpP3cA_XF9x5KVrGwzhLw_9uNJcsjOLdaCrnzplb4v56-wxWj0vn2YPq8gkCvooFXEslS5NWgIg2pxkSTZXFkDbHHO7pqwUpGIQVgqLa0EwwiaN11ZIhGTKbo53d127P1Doi8YFQ3WNntpDKESWCpmAUvofqFQgdKbkiN4eUTOKCONrxa5zDXZDIaD48l_M5Hz-7X-RfALNRXo9</recordid><startdate>20150101</startdate><enddate>20150101</enddate><creator>Arias, Karen S</creator><creator>Climent, Maria J</creator><creator>Corma, Avelino</creator><creator>Iborra, Sara</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7QO</scope><scope>7ST</scope><scope>7TG</scope><scope>7U6</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>KL.</scope><scope>P64</scope><scope>SOI</scope><scope>7SP</scope><scope>7SU</scope><scope>7TB</scope><scope>L7M</scope></search><sort><creationdate>20150101</creationdate><title>Synthesis of high quality alkyl naphthenic kerosene by reacting an oil refinery with a biomass refinery stream</title><author>Arias, Karen S ; Climent, Maria J ; Corma, Avelino ; Iborra, Sara</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c370t-5122479bc5b00aaf8e4bef87f009f8a8fde6b1e7201f41fad1e0bc5c52df14a03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Alkylation</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Kerosene</topic><topic>Porosity</topic><topic>Refineries</topic><topic>Synthesis</topic><topic>Titanium dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Arias, Karen S</creatorcontrib><creatorcontrib>Climent, Maria J</creatorcontrib><creatorcontrib>Corma, Avelino</creatorcontrib><creatorcontrib>Iborra, Sara</creatorcontrib><collection>CrossRef</collection><collection>Biotechnology Research Abstracts</collection><collection>Environment Abstracts</collection><collection>Meteorological &amp; Geoastrophysical Abstracts</collection><collection>Sustainability Science Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Meteorological &amp; Geoastrophysical Abstracts - Academic</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Environment Abstracts</collection><collection>Electronics &amp; Communications Abstracts</collection><collection>Environmental Engineering Abstracts</collection><collection>Mechanical &amp; Transportation Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Energy &amp; environmental science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Arias, Karen S</au><au>Climent, Maria J</au><au>Corma, Avelino</au><au>Iborra, Sara</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of high quality alkyl naphthenic kerosene by reacting an oil refinery with a biomass refinery stream</atitle><jtitle>Energy &amp; environmental science</jtitle><date>2015-01-01</date><risdate>2015</risdate><volume>8</volume><issue>1</issue><spage>317</spage><epage>331</epage><pages>317-331</pages><issn>1754-5692</issn><eissn>1754-5706</eissn><abstract>Alkylation of aromatics with HMF is a new route for the synthesis of biofuels. Alkylation of toluene with HMF has been studied in the presence of large pore (HBeta, USY and Mordenite), delaminated zeolites as well as on mesoporous aluminosilicates. In all cases a mixture of monoalkylated products of 5-(o-, m- and p-methyl)benzylfuran-2-carbaldehyde and OBMF coming from self etherification of HMF were obtained. Large pore 3D (USY) and especially 2D (ITQ-2) zeolites are active and selective catalysts for this transformation. The alkylation reaction was extended successfully to other substituted benzenes as well as to a heavy reformate mixture as source aromatic compounds, achieving 91% yield of alkylated products with 93% selectivity. Further hydrodeoxygenation of alkylated compounds in a fixed bed continuous reactor was performed using Pt/C and Pt/TiO sub(2) as catalysts allowing to obtain a hydrocarbon mixture containing alkylcyclohexane compounds that can be used as high quality kerosene.</abstract><doi>10.1039/c4ee03194f</doi><tpages>15</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 1754-5692
ispartof Energy & environmental science, 2015-01, Vol.8 (1), p.317-331
issn 1754-5692
1754-5706
language eng
recordid cdi_proquest_miscellaneous_1651430779
source Royal Society of Chemistry Journals
subjects Alkylation
Catalysis
Catalysts
Kerosene
Porosity
Refineries
Synthesis
Titanium dioxide
title Synthesis of high quality alkyl naphthenic kerosene by reacting an oil refinery with a biomass refinery stream
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-16T09%3A24%3A52IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20of%20high%20quality%20alkyl%20naphthenic%20kerosene%20by%20reacting%20an%20oil%20refinery%20with%20a%20biomass%20refinery%20stream&rft.jtitle=Energy%20&%20environmental%20science&rft.au=Arias,%20Karen%20S&rft.date=2015-01-01&rft.volume=8&rft.issue=1&rft.spage=317&rft.epage=331&rft.pages=317-331&rft.issn=1754-5692&rft.eissn=1754-5706&rft_id=info:doi/10.1039/c4ee03194f&rft_dat=%3Cproquest_cross%3E1647019674%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c370t-5122479bc5b00aaf8e4bef87f009f8a8fde6b1e7201f41fad1e0bc5c52df14a03%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1647019674&rft_id=info:pmid/&rfr_iscdi=true