Modification of the kinetics for modeling substrate storage and biomass growth mechanism in activated sludge system under aerobic condition

• Published in: Chemical engineering science 2012-08, Vol.78, p.75-81
• Main Authors: Fan, Ji, Vanrolleghem, Peter A., Lu, Shuguang, Qiu, Zhaofu
• Format: Article
• Language: English
• Subjects: Acetates; Activated sludge; Aircraft components; Applied sciences; Biomass; Calibration; Chemical engineering; chemical oxygen demand; Exact sciences and technology; General purification processes; Kinetics; Mathematical modeling; Mathematical models; oxygen; Oxygen demand; Oxygen uptake rate (OUR); Parameter identification; Pollution; prediction; Sewerage works: sewers, sewage treatment plants, outfalls; Simulation; Simultaneous substrate storage and growth (SSSG); wastewater treatment; Wastewaters; Water treatment and pollution
• ISSN: 0009-2509; 1873-4405
• DOI: 10.1016/j.ces.2012.05.004

Based on the activated sludge model no.3 (ASM3), a new kinetic expression describing substrate removal and biomass growth mechanism occurring in activated sludge system under aerobic condition was established. The new model proposed that under feast condition, one part of substrate was utilized directly for biomass growth and the other part was stored as internal storage products and simultaneously the storage products were used for biomass growth. The model was successfully calibrated on oxygen uptake rate (OUR) data and off-line soluble chemical oxygen demand (COD) dynamic variations obtained from batch experiments with biomass from a full-scale wastewater treatment plant (WWTP). OUR predictions with the calibrated model could reasonably describe the OUR profile after pulse addition of acetate, i.e., the OUR transiently reached a very high level, and then increased gradually to a maximum level until the initial substrate was taken up for storage and biomass growth. This new model also, for the first time, highlighted the significant effect of the biomass storage products concentration before pulse addition of acetate on OUR profile. ► During feast phase the SSSG process includes storage and growth using XSTO or substrate processes. ► There is no Monod inhibition function for the consumption of XSTO. ► The XSTO concentration before pulse addition of acetate can affect OUR profile.