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Metal-Organic Framework Templated Inorganic Sorbents for Rapid and Efficient Extraction of Heavy Metals

An innovative wet‐treatment with Na2S transforms two indium metal‐organic frameworks (MOFs) into a series of porous inorganic sorbents. These MOF‐templated materials display remarkable affinity for heavy metals with saturation occurring in less than 1 h. The saturation capacity for Hg(II) exceeds 2...

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Published in:	Advanced materials (Weinheim) 2014-12, Vol.26 (47), p.7993-7997
Main Authors:	Abney, C. W., Gilhula, J. C., Lu, K., Lin, W.
Format:	Article
Language:	English
Subjects:	Adsorption Affinity environmental remediation Extraction Heavy metals Indium Indium - chemistry mercury Mercury - chemistry Metal-organic frameworks Metals, Heavy - chemistry Organometallic Compounds - chemistry Porosity Saturation Sorbents Sulfides - chemistry Transforms water decontamination Water Pollutants, Chemical - chemistry X-Ray Absorption Spectroscopy
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creator	Abney, C. W. Gilhula, J. C. Lu, K. Lin, W.
description	An innovative wet‐treatment with Na2S transforms two indium metal‐organic frameworks (MOFs) into a series of porous inorganic sorbents. These MOF‐templated materials display remarkable affinity for heavy metals with saturation occurring in less than 1 h. The saturation capacity for Hg(II) exceeds 2 g g‐1, more than doubling the best thiol‐functionalized sorbents in the literature.
doi_str_mv	10.1002/adma.201403428
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subjects	Adsorption Affinity environmental remediation Extraction Heavy metals Indium Indium - chemistry mercury Mercury - chemistry Metal-organic frameworks Metals, Heavy - chemistry Organometallic Compounds - chemistry Porosity Saturation Sorbents Sulfides - chemistry Transforms water decontamination Water Pollutants, Chemical - chemistry X-Ray Absorption Spectroscopy
title	Metal-Organic Framework Templated Inorganic Sorbents for Rapid and Efficient Extraction of Heavy Metals
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