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Rhodium Nanoparticles for Ultraviolet Plasmonics
The nonoxidizing catalytic noble metal rhodium is introduced for ultraviolet plasmonics. Planar tripods of 8 nm Rh nanoparticles, synthesized by a modified polyol reduction method, have a calculated local surface plasmon resonance near 330 nm. By attaching p-aminothiophenol, local field-enhanced Ram...
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| Published in: | Nano letters 2015-02, Vol.15 (2), p.1095-1100 |
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| Main Authors: | , , , , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-a350t-ecab7895e90c532e7217bba02744def9919d099a06fb5bf820a182ca3210e9643 |
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| cites | cdi_FETCH-LOGICAL-a350t-ecab7895e90c532e7217bba02744def9919d099a06fb5bf820a182ca3210e9643 |
| container_end_page | 1100 |
| container_issue | 2 |
| container_start_page | 1095 |
| container_title | Nano letters |
| container_volume | 15 |
| creator | Watson, Anne M Zhang, Xiao Alcaraz de la Osa, Rodrigo Sanz, Juan Marcos González, Francisco Moreno, Fernando Finkelstein, Gleb Liu, Jie Everitt, Henry O |
| description | The nonoxidizing catalytic noble metal rhodium is introduced for ultraviolet plasmonics. Planar tripods of 8 nm Rh nanoparticles, synthesized by a modified polyol reduction method, have a calculated local surface plasmon resonance near 330 nm. By attaching p-aminothiophenol, local field-enhanced Raman spectra and accelerated photodamage were observed under near-resonant ultraviolet illumination, while charge transfer simultaneously increased fluorescence for up to 13 min. The combined local field enhancement and charge transfer demonstrate essential steps toward plasmonically enhanced ultraviolet photocatalysis. |
| doi_str_mv | 10.1021/nl5040623 |
| format | article |
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| language | eng |
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| source | Access via American Chemical Society |
| title | Rhodium Nanoparticles for Ultraviolet Plasmonics |
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