Synthesis of spiroaminals by bimetallic Au/Sc relay catalysis: TMS as a traceless controlling group

An efficient synthesis of spiroaminals over fused aminals has been successfully developed by bimetallic Au/Sc catalysis by using TMS as a traceless controlling group.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2014-10, Vol.50 (81), p.12084-12087
Main Authors: Zhang, Shuo, Xu, Zhengliang, Jia, Jiong, Tung, Chen-Ho, Xu, Zhenghu
Format: Article
Language:English
Subjects:
Bimetals
Catalysis
Gold
Relay
Scandium
Synthesis
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Description
Summary:An efficient synthesis of spiroaminals over fused aminals has been successfully developed by bimetallic Au/Sc catalysis by using TMS as a traceless controlling group.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc05610h