Probing the dead layer thickness and its effect on the structure and magnetic properties in La2/3Ca1/3MnO3 thin films

• Published in: Thin solid films 2013-10, Vol.545, p.89-93
• Main Authors: Xie, Q.Y., Wu, X.S., Li, J., Lv, B., Gao, J.
• Format: Article
• Language: English
• Subjects: Condensed matter: structure, mechanical and thermal properties; Diffraction; Exact sciences and technology; Grazing incidence X-ray diffraction; Lanthanum calcium manganese oxide; Magnetic properties; Physics; Reflectivity; Saturation (magnetic); Structural properties; Structure and morphology; thickness; Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties); Thin film structure and morphology; Thin films; Transport properties; X-rays; Zirconium dioxide
• ISSN: 0040-6090; 1879-2731
• DOI: 10.1016/j.tsf.2013.07.036

The microstructure of La2/3Ca1/3MnO3 films of 42-nm thickness, grown on (001) SrTiO3, (001) LaAlO3 and (001) Y-stabilized ZrO2 substrates, has been studied with considering the existence of surface/interface dead layers. The dead layer thickness deduced from X-ray reflectivity is in good agreement with that from transport property measurements. Due to the surface and interface layers, the spontaneous emergence of fully relaxed and coherently strained films is further demonstrated by grazing incidence X-ray diffraction. The smallest saturation magnetization and the largest coercive filed is obtained in La2/3Ca1/3MnO3 film grown on LaAlO3 substrate, which has the thickest dead layer thickness. Moreover, the effect of dead layer on the magnetic and transport properties of La2/3Ca1/3MnO3 film grown on Y-stabilized ZrO2 substrate has been carefully analyzed. •The surface/interface dead layer thickness of La2/3Ca1/3MnO3 film is deduced.•The inhomogeneous strain state is studied by grazing incidence X-ray diffraction.•The microstructure correlates strongly with the magnetic properties.•The magnetic dead layer is notably thicker than the electrical dead layer.