Three Polyoxometalate-Based Coordination Polymers Constructed from the Same Dimetallic Cyclic Building Block
The reactions of silicotungstate, 2,5‐bis(3‐pyridyl)‐1,3,4‐oxadiazole (3‐bpo), and copper, cobalt, or nickel acetate under hydrothermal condition yield the three compounds [(SiW12O40)Cu2(3‐bpo)2(C5H4NCOOH)2]·H2O (1), [(SiW12O40)Co2(3‐bpo)2(C5H4NCOOH)2(H2O)2]·2H2O (2), and [(SiW12O40)Ni2(3‐bpo)2(C5H4...
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Published in: | European journal of inorganic chemistry 2015-01, Vol.2015 (3), p.488-493 |
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creator | Gu, Min Ren, Yuanhang Hu, Yichen Tang, Min Kong, Zuping Yue, Bin He, Heyong |
description | The reactions of silicotungstate, 2,5‐bis(3‐pyridyl)‐1,3,4‐oxadiazole (3‐bpo), and copper, cobalt, or nickel acetate under hydrothermal condition yield the three compounds [(SiW12O40)Cu2(3‐bpo)2(C5H4NCOOH)2]·H2O (1), [(SiW12O40)Co2(3‐bpo)2(C5H4NCOOH)2(H2O)2]·2H2O (2), and [(SiW12O40)Ni2(3‐bpo)2(C5H4NCOOH)2(H2O)2]·3H2O (3), respectively, in which the nicotinic acid ligands are generated from the in situ decomposition of 3‐bpo during the hydrothermal process. In the three structures, the polyoxometalate (POM) serves as the center and is imbedded within the dimetallic cyclic [M2(3‐bpo)2(C5H4NCOOH)2]4+ moiety through coordination bonds to form infinite one‐dimensional (1D) supramolecular snadwich‐like structures. Owing to the difference in the metal ions, the packing style of [Cu2(3‐bpo)2(C5H4NCOOH)2]4+ is different from that of [M2(3‐bpo)2(C5H4NCOOH)2]4+ (M = Co, Ni). The electrochemical behaviors of compounds 1–3 were studied by cyclic voltammetry.
Three polyoxometalate‐based (POM‐based) coordination polymers containing a similar type of building block, [M2(3‐bpo)2(C5H4NCOOH)2]4+ [M = Cu, Co, Ni; 3‐bpo = 2,5‐bis(3‐pyridyl)‐1,3,4‐oxadiazole], are hydrothermally synthesized. These polymers are characterized, and their electrochemical behaviors are studied by cyclic voltammetry. |
doi_str_mv | 10.1002/ejic.201402938 |
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Three polyoxometalate‐based (POM‐based) coordination polymers containing a similar type of building block, [M2(3‐bpo)2(C5H4NCOOH)2]4+ [M = Cu, Co, Ni; 3‐bpo = 2,5‐bis(3‐pyridyl)‐1,3,4‐oxadiazole], are hydrothermally synthesized. These polymers are characterized, and their electrochemical behaviors are studied by cyclic voltammetry.</description><identifier>ISSN: 1434-1948</identifier><identifier>EISSN: 1099-0682</identifier><identifier>DOI: 10.1002/ejic.201402938</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Acetal resins ; Bridging ligands ; Coordination polymers ; Copper ; Electrochemical analysis ; Hydrothermal synthesis ; Ligands ; Nickel ; Nicotinic acid ; Polyoxometalates ; Voltammetry</subject><ispartof>European journal of inorganic chemistry, 2015-01, Vol.2015 (3), p.488-493</ispartof><rights>Copyright © 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5288-ac99e7436423a511a1df30a23a693066388a1e14f3290345ed86838e44cbaf13</citedby><cites>FETCH-LOGICAL-c5288-ac99e7436423a511a1df30a23a693066388a1e14f3290345ed86838e44cbaf13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Gu, Min</creatorcontrib><creatorcontrib>Ren, Yuanhang</creatorcontrib><creatorcontrib>Hu, Yichen</creatorcontrib><creatorcontrib>Tang, Min</creatorcontrib><creatorcontrib>Kong, Zuping</creatorcontrib><creatorcontrib>Yue, Bin</creatorcontrib><creatorcontrib>He, Heyong</creatorcontrib><title>Three Polyoxometalate-Based Coordination Polymers Constructed from the Same Dimetallic Cyclic Building Block</title><title>European journal of inorganic chemistry</title><addtitle>Eur. J. Inorg. Chem</addtitle><description>The reactions of silicotungstate, 2,5‐bis(3‐pyridyl)‐1,3,4‐oxadiazole (3‐bpo), and copper, cobalt, or nickel acetate under hydrothermal condition yield the three compounds [(SiW12O40)Cu2(3‐bpo)2(C5H4NCOOH)2]·H2O (1), [(SiW12O40)Co2(3‐bpo)2(C5H4NCOOH)2(H2O)2]·2H2O (2), and [(SiW12O40)Ni2(3‐bpo)2(C5H4NCOOH)2(H2O)2]·3H2O (3), respectively, in which the nicotinic acid ligands are generated from the in situ decomposition of 3‐bpo during the hydrothermal process. In the three structures, the polyoxometalate (POM) serves as the center and is imbedded within the dimetallic cyclic [M2(3‐bpo)2(C5H4NCOOH)2]4+ moiety through coordination bonds to form infinite one‐dimensional (1D) supramolecular snadwich‐like structures. Owing to the difference in the metal ions, the packing style of [Cu2(3‐bpo)2(C5H4NCOOH)2]4+ is different from that of [M2(3‐bpo)2(C5H4NCOOH)2]4+ (M = Co, Ni). The electrochemical behaviors of compounds 1–3 were studied by cyclic voltammetry.
Three polyoxometalate‐based (POM‐based) coordination polymers containing a similar type of building block, [M2(3‐bpo)2(C5H4NCOOH)2]4+ [M = Cu, Co, Ni; 3‐bpo = 2,5‐bis(3‐pyridyl)‐1,3,4‐oxadiazole], are hydrothermally synthesized. These polymers are characterized, and their electrochemical behaviors are studied by cyclic voltammetry.</description><subject>Acetal resins</subject><subject>Bridging ligands</subject><subject>Coordination polymers</subject><subject>Copper</subject><subject>Electrochemical analysis</subject><subject>Hydrothermal synthesis</subject><subject>Ligands</subject><subject>Nickel</subject><subject>Nicotinic acid</subject><subject>Polyoxometalates</subject><subject>Voltammetry</subject><issn>1434-1948</issn><issn>1099-0682</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqFkE1v1DAQhiMEEqVw5Rypl16yHX-ufeyG0k8VJFaCm2W8k9ZbJ27tRHT_fb1dVFVcOM2M9TyvrLeqPhOYEQB6hGvvZhQIB6qZelPtEdC6Aano27JzxhuiuXpffch5DQAMmNyrwvI2IdbfY9jEx9jjaIMdsVnYjKu6jTGt_GBHH4dnpMeUy-uQxzS5sRBdin093mL9w_ZYf_HPAcG7ut247VhMPpSEm3oRorv7WL3rbMj46e_cr5ZfT5btWXP17fS8Pb5qnKBKNdZpjXPOJKfMCkIsWXUMbDmkZiAlU8oSJLxjVAPjAldKKqaQc_fbdoTtV4e72PsUHybMo-l9dhiCHTBO2RApAYRWihb04B90Hac0lM8ZMpcKKBFCFGq2o1yKOSfszH3yvU0bQ8Bsuzfb7s1L90XQO-GPD7j5D21OLs7b126zc30e8fHFtenOyDmbC_Pz-tRoSpbi8te1IewJN16W1w</recordid><startdate>201501</startdate><enddate>201501</enddate><creator>Gu, Min</creator><creator>Ren, Yuanhang</creator><creator>Hu, Yichen</creator><creator>Tang, Min</creator><creator>Kong, Zuping</creator><creator>Yue, Bin</creator><creator>He, Heyong</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>FR3</scope><scope>KR7</scope></search><sort><creationdate>201501</creationdate><title>Three Polyoxometalate-Based Coordination Polymers Constructed from the Same Dimetallic Cyclic Building Block</title><author>Gu, Min ; Ren, Yuanhang ; Hu, Yichen ; Tang, Min ; Kong, Zuping ; Yue, Bin ; He, Heyong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5288-ac99e7436423a511a1df30a23a693066388a1e14f3290345ed86838e44cbaf13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Acetal resins</topic><topic>Bridging ligands</topic><topic>Coordination polymers</topic><topic>Copper</topic><topic>Electrochemical analysis</topic><topic>Hydrothermal synthesis</topic><topic>Ligands</topic><topic>Nickel</topic><topic>Nicotinic acid</topic><topic>Polyoxometalates</topic><topic>Voltammetry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gu, Min</creatorcontrib><creatorcontrib>Ren, Yuanhang</creatorcontrib><creatorcontrib>Hu, Yichen</creatorcontrib><creatorcontrib>Tang, Min</creatorcontrib><creatorcontrib>Kong, Zuping</creatorcontrib><creatorcontrib>Yue, Bin</creatorcontrib><creatorcontrib>He, Heyong</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><jtitle>European journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gu, Min</au><au>Ren, Yuanhang</au><au>Hu, Yichen</au><au>Tang, Min</au><au>Kong, Zuping</au><au>Yue, Bin</au><au>He, Heyong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Three Polyoxometalate-Based Coordination Polymers Constructed from the Same Dimetallic Cyclic Building Block</atitle><jtitle>European journal of inorganic chemistry</jtitle><addtitle>Eur. J. Inorg. Chem</addtitle><date>2015-01</date><risdate>2015</risdate><volume>2015</volume><issue>3</issue><spage>488</spage><epage>493</epage><pages>488-493</pages><issn>1434-1948</issn><eissn>1099-0682</eissn><abstract>The reactions of silicotungstate, 2,5‐bis(3‐pyridyl)‐1,3,4‐oxadiazole (3‐bpo), and copper, cobalt, or nickel acetate under hydrothermal condition yield the three compounds [(SiW12O40)Cu2(3‐bpo)2(C5H4NCOOH)2]·H2O (1), [(SiW12O40)Co2(3‐bpo)2(C5H4NCOOH)2(H2O)2]·2H2O (2), and [(SiW12O40)Ni2(3‐bpo)2(C5H4NCOOH)2(H2O)2]·3H2O (3), respectively, in which the nicotinic acid ligands are generated from the in situ decomposition of 3‐bpo during the hydrothermal process. In the three structures, the polyoxometalate (POM) serves as the center and is imbedded within the dimetallic cyclic [M2(3‐bpo)2(C5H4NCOOH)2]4+ moiety through coordination bonds to form infinite one‐dimensional (1D) supramolecular snadwich‐like structures. Owing to the difference in the metal ions, the packing style of [Cu2(3‐bpo)2(C5H4NCOOH)2]4+ is different from that of [M2(3‐bpo)2(C5H4NCOOH)2]4+ (M = Co, Ni). The electrochemical behaviors of compounds 1–3 were studied by cyclic voltammetry.
Three polyoxometalate‐based (POM‐based) coordination polymers containing a similar type of building block, [M2(3‐bpo)2(C5H4NCOOH)2]4+ [M = Cu, Co, Ni; 3‐bpo = 2,5‐bis(3‐pyridyl)‐1,3,4‐oxadiazole], are hydrothermally synthesized. These polymers are characterized, and their electrochemical behaviors are studied by cyclic voltammetry.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/ejic.201402938</doi><tpages>6</tpages></addata></record> |
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subjects | Acetal resins Bridging ligands Coordination polymers Copper Electrochemical analysis Hydrothermal synthesis Ligands Nickel Nicotinic acid Polyoxometalates Voltammetry |
title | Three Polyoxometalate-Based Coordination Polymers Constructed from the Same Dimetallic Cyclic Building Block |
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