Three Polyoxometalate-Based Coordination Polymers Constructed from the Same Dimetallic Cyclic Building Block

The reactions of silicotungstate, 2,5‐bis(3‐pyridyl)‐1,3,4‐oxadiazole (3‐bpo), and copper, cobalt, or nickel acetate under hydrothermal condition yield the three compounds [(SiW12O40)Cu2(3‐bpo)2(C5H4NCOOH)2]·H2O (1), [(SiW12O40)Co2(3‐bpo)2(C5H4NCOOH)2(H2O)2]·2H2O (2), and [(SiW12O40)Ni2(3‐bpo)2(C5H4...

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Published in:European journal of inorganic chemistry 2015-01, Vol.2015 (3), p.488-493
Main Authors: Gu, Min, Ren, Yuanhang, Hu, Yichen, Tang, Min, Kong, Zuping, Yue, Bin, He, Heyong
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container_title European journal of inorganic chemistry
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creator Gu, Min
Ren, Yuanhang
Hu, Yichen
Tang, Min
Kong, Zuping
Yue, Bin
He, Heyong
description The reactions of silicotungstate, 2,5‐bis(3‐pyridyl)‐1,3,4‐oxadiazole (3‐bpo), and copper, cobalt, or nickel acetate under hydrothermal condition yield the three compounds [(SiW12O40)Cu2(3‐bpo)2(C5H4NCOOH)2]·H2O (1), [(SiW12O40)Co2(3‐bpo)2(C5H4NCOOH)2(H2O)2]·2H2O (2), and [(SiW12O40)Ni2(3‐bpo)2(C5H4NCOOH)2(H2O)2]·3H2O (3), respectively, in which the nicotinic acid ligands are generated from the in situ decomposition of 3‐bpo during the hydrothermal process. In the three structures, the polyoxometalate (POM) serves as the center and is imbedded within the dimetallic cyclic [M2(3‐bpo)2(C5H4NCOOH)2]4+ moiety through coordination bonds to form infinite one‐dimensional (1D) supramolecular snadwich‐like structures. Owing to the difference in the metal ions, the packing style of [Cu2(3‐bpo)2(C5H4NCOOH)2]4+ is different from that of [M2(3‐bpo)2(C5H4NCOOH)2]4+ (M = Co, Ni). The electrochemical behaviors of compounds 1–3 were studied by cyclic voltammetry. Three polyoxometalate‐based (POM‐based) coordination polymers containing a similar type of building block, [M2(3‐bpo)2(C5H4NCOOH)2]4+ [M = Cu, Co, Ni; 3‐bpo = 2,5‐bis(3‐pyridyl)‐1,3,4‐oxadiazole], are hydrothermally synthesized. These polymers are characterized, and their electrochemical behaviors are studied by cyclic voltammetry.
doi_str_mv 10.1002/ejic.201402938
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In the three structures, the polyoxometalate (POM) serves as the center and is imbedded within the dimetallic cyclic [M2(3‐bpo)2(C5H4NCOOH)2]4+ moiety through coordination bonds to form infinite one‐dimensional (1D) supramolecular snadwich‐like structures. Owing to the difference in the metal ions, the packing style of [Cu2(3‐bpo)2(C5H4NCOOH)2]4+ is different from that of [M2(3‐bpo)2(C5H4NCOOH)2]4+ (M = Co, Ni). The electrochemical behaviors of compounds 1–3 were studied by cyclic voltammetry. Three polyoxometalate‐based (POM‐based) coordination polymers containing a similar type of building block, [M2(3‐bpo)2(C5H4NCOOH)2]4+ [M = Cu, Co, Ni; 3‐bpo = 2,5‐bis(3‐pyridyl)‐1,3,4‐oxadiazole], are hydrothermally synthesized. 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J. Inorg. Chem</addtitle><description>The reactions of silicotungstate, 2,5‐bis(3‐pyridyl)‐1,3,4‐oxadiazole (3‐bpo), and copper, cobalt, or nickel acetate under hydrothermal condition yield the three compounds [(SiW12O40)Cu2(3‐bpo)2(C5H4NCOOH)2]·H2O (1), [(SiW12O40)Co2(3‐bpo)2(C5H4NCOOH)2(H2O)2]·2H2O (2), and [(SiW12O40)Ni2(3‐bpo)2(C5H4NCOOH)2(H2O)2]·3H2O (3), respectively, in which the nicotinic acid ligands are generated from the in situ decomposition of 3‐bpo during the hydrothermal process. In the three structures, the polyoxometalate (POM) serves as the center and is imbedded within the dimetallic cyclic [M2(3‐bpo)2(C5H4NCOOH)2]4+ moiety through coordination bonds to form infinite one‐dimensional (1D) supramolecular snadwich‐like structures. Owing to the difference in the metal ions, the packing style of [Cu2(3‐bpo)2(C5H4NCOOH)2]4+ is different from that of [M2(3‐bpo)2(C5H4NCOOH)2]4+ (M = Co, Ni). The electrochemical behaviors of compounds 1–3 were studied by cyclic voltammetry. Three polyoxometalate‐based (POM‐based) coordination polymers containing a similar type of building block, [M2(3‐bpo)2(C5H4NCOOH)2]4+ [M = Cu, Co, Ni; 3‐bpo = 2,5‐bis(3‐pyridyl)‐1,3,4‐oxadiazole], are hydrothermally synthesized. 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J. Inorg. Chem</addtitle><date>2015-01</date><risdate>2015</risdate><volume>2015</volume><issue>3</issue><spage>488</spage><epage>493</epage><pages>488-493</pages><issn>1434-1948</issn><eissn>1099-0682</eissn><abstract>The reactions of silicotungstate, 2,5‐bis(3‐pyridyl)‐1,3,4‐oxadiazole (3‐bpo), and copper, cobalt, or nickel acetate under hydrothermal condition yield the three compounds [(SiW12O40)Cu2(3‐bpo)2(C5H4NCOOH)2]·H2O (1), [(SiW12O40)Co2(3‐bpo)2(C5H4NCOOH)2(H2O)2]·2H2O (2), and [(SiW12O40)Ni2(3‐bpo)2(C5H4NCOOH)2(H2O)2]·3H2O (3), respectively, in which the nicotinic acid ligands are generated from the in situ decomposition of 3‐bpo during the hydrothermal process. In the three structures, the polyoxometalate (POM) serves as the center and is imbedded within the dimetallic cyclic [M2(3‐bpo)2(C5H4NCOOH)2]4+ moiety through coordination bonds to form infinite one‐dimensional (1D) supramolecular snadwich‐like structures. Owing to the difference in the metal ions, the packing style of [Cu2(3‐bpo)2(C5H4NCOOH)2]4+ is different from that of [M2(3‐bpo)2(C5H4NCOOH)2]4+ (M = Co, Ni). The electrochemical behaviors of compounds 1–3 were studied by cyclic voltammetry. Three polyoxometalate‐based (POM‐based) coordination polymers containing a similar type of building block, [M2(3‐bpo)2(C5H4NCOOH)2]4+ [M = Cu, Co, Ni; 3‐bpo = 2,5‐bis(3‐pyridyl)‐1,3,4‐oxadiazole], are hydrothermally synthesized. These polymers are characterized, and their electrochemical behaviors are studied by cyclic voltammetry.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/ejic.201402938</doi><tpages>6</tpages></addata></record>
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subjects Acetal resins
Bridging ligands
Coordination polymers
Copper
Electrochemical analysis
Hydrothermal synthesis
Ligands
Nickel
Nicotinic acid
Polyoxometalates
Voltammetry
title Three Polyoxometalate-Based Coordination Polymers Constructed from the Same Dimetallic Cyclic Building Block
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