Graphene-encapsulated SnO2 hollow spheres as high-performance anode materials for lithium ion batteries

Graphene-encapsulated SnO2 hollow spheres (GE-SnO2 HS) are synthesized by a simple electrostatic self-assembly process. The prepared composite consists of SnO2 hollow spheres (SnO2 HS) in the interior, which are encapsulated by flexible ultra-thin graphene shells at the exterior. This novel architec...

Full description

Saved in:
Bibliographic Details
Published in:Ceramics international 2014-11, Vol.40 (9), p.13903-13910
Main Authors: Yang, Hang, Hou, Zhaohui, Zhou, Ningbo, He, Binhong, Cao, Jianguo, Kuang, Yafei
Format: Article
Language:English
Subjects:
B. Nanocomposites
C. Electrical properties
Ceramics
Current density
E. Batteries
Graphene
Lithium-ion batteries
Nanocomposites
Self assembly
Shells
Tin dioxide
Tin oxides
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Graphene-encapsulated SnO2 hollow spheres (GE-SnO2 HS) are synthesized by a simple electrostatic self-assembly process. The prepared composite consists of SnO2 hollow spheres (SnO2 HS) in the interior, which are encapsulated by flexible ultra-thin graphene shells at the exterior. This novel architecture is expected to buffer large volume changes and effectively prevent the detachment and agglomeration of SnO2 during the lithiation and delithiation processes. The GE-SnO2 HS composite exhibits much better electrochemical performance than bare SnO2 HS. In addition, the composite delivers a high reversible capacity of 422mAhg−1 after 100 cycles at a current density of 158mAg−1 and a capacity of 237mAhg−1 after 30 cycles at a higher current density of 1580mAg−1. These results suggest that the GE-SnO2 HS composite can provide new opportunities to enhance the properties of tin-based materials for use in high-capacity lithium ion batteries.
ISSN:0272-8842
1873-3956
DOI:10.1016/j.ceramint.2014.05.109