Sensing devices based on ZnO hexagonal tube-like nanostructures grown on p-GaN heterojunction by wet thermal evaporation

• Published in: Thin solid films 2013-07, Vol.540, p.212-220
• Main Authors: Abdulgafour, H.I., Hassan, Z., Yam, F.K., Chin, C.W.
• Format: Article
• Language: English
• Subjects: Catalysis; Catalysts: preparations and properties; Characterization; Chemistry; Condensed matter: electronic structure, electrical, magnetic, and optical properties; Cross-disciplinary physics: materials science; rheology; Dark current; Evaporation; Exact sciences and technology; Gas sensor; General and physical chemistry; Heterojunctions; Heterostructures; Illumination; Materials science; Methods of nanofabrication; Nanostructure; Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation; Optical properties of specific thin films; Other semiconductors; Palladium; Physics; p–n heterojunction; Specific materials; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; UV detector; Zinc oxide; ZnO nanostructures
• ISSN: 0040-6090; 1879-2731
• DOI: 10.1016/j.tsf.2013.05.091

High-quality ZnO hexagonal tube-like nanostructures grown on p-type GaN heterojunction have been synthesized for sensing applications through a low-cost catalyst-free process by thermal evaporation at 800°C. The morphological, structural, and optical properties of the ZnO heterostructures have been examined. In this study, Pd/ZnO/Pd metal–semiconductor–metal gas sensor has been fabricated based on the ZnO tube-like nanostructures. The sensitivity of ZnO/p-GaN heterostructures is measured at different flow rates (25, 50, 100, and 150sccm) of H2 gas at room temperature. The highest response of the ZnO/p-GaN sensor was 1250%, when 150sccm of H2 gas was injected. In addition, Pd/Al n-ZnO/p-GaN heterojunction as an ultraviolet photodiode is demonstrated. The current–voltage curve of the heterojunction demonstrates obvious rectifying behavior in the dark and under illumination. For illumination conditions, one light source of wavelength 365nm and another at 400nm were used, sweeping the bias voltage from +4 to −4V. Under UV light at 365nm the current was almost 12 times greater than that in the dark, while under UV light at 400nm the current was 2.2 times greater than that in the dark at 3V. •High-quality ZnO hexagonal tube-like-nanostructures on p-type GaN heterojunction•Nanostructures synthesized by wet thermal evaporation method•Morphological, structural, and optical properties of ZnO heterostructures examined•Pd/ZnO/Pd hydrogen gas sensor and Pd/Al n-ZnO/p-GaN UV photodiode fabricated