Determination of eight pesticides of varying polarity in surface waters using solid phase extraction with multiwalled carbon nanotubes and liquid chromatography-linear ion trap mass spectrometry

We describe a MWCNT-based method for the solid-phase extraction of eight pesticides from environmental water samples. The analytes are extracted from 100 mL samples at pH 5.0 (containing 5 mmol L −1 of KCl) by passing the solution through a column filled with 20 mg of multiwalled carbon nanotubes. F...

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Bibliographic Details
Published in:Mikrochimica acta (1966) 2015-01, Vol.182 (1-2), p.95-103
Main Authors: Dahane, Soraya, Gil García, María Dolores, Uclés Moreno, Ana, Martínez Galera, María, Socías Viciana, María del Mar, Derdour, Aicha
Format: Article
Language:English
Subjects:
Analytical Chemistry
Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Enrichment
Extraction
Ionization
Mass spectrometry
Microengineering
Multi wall carbon nanotubes
Nanochemistry
Nanotechnology
Nanotubes
Original Paper
Pesticides
Polarity
Surface water
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Summary:We describe a MWCNT-based method for the solid-phase extraction of eight pesticides from environmental water samples. The analytes are extracted from 100 mL samples at pH 5.0 (containing 5 mmol L −1 of KCl) by passing the solution through a column filled with 20 mg of multiwalled carbon nanotubes. Following elution, the pesticides were determined by LC and electrospray ionization hybrid quadrupole linear ion trap MS. Two selected reaction monitoring transitions were monitored per compound, the most intense one being used for quantification and the second one for confirmation. In addition, an information-dependent acquisition experiment was performed for unequivocal confirmation of positive findings. Matrix effect was not found in real waters and therefore the quantitation was carried out with calibration graphs built with solvent based standards. Except for cymoxanil, the detection and quantitation limits in surface waters are in the range from 0.3 to 9.5 ng L −1 and 1.6 to 45.2 ng L −1 , respectively. Recoveries from spiked ultrapure water are ~100 %, except for the most polar pesticides methomyl and cymoxanil. The same behavior is found for real water samples (except for phosalone). The relative standard deviation is
ISSN:0026-3672
1436-5073
DOI:10.1007/s00604-014-1290-x