Performance of magnetic activated carbon composite as peroxymonosulfate activator and regenerable adsorbent via sulfate radical-mediated oxidation processes

• Published in: Journal of hazardous materials 2015-03, Vol.284, p.1-9
• Main Authors: Oh, Wen-Da, Lua, Shun-Kuang, Dong, Zhili, Lim, Teik-Thye
• Format: Article
• Language: English
• Subjects: Activated carbon regeneration; Activation; Adsorbents; Adsorption; Carbon - chemistry; Catalysts; Charcoal - chemistry; Crystallization; Degradation; Hydrogen-Ion Concentration; Kinetics; Magnetic activated carbon composite; Magnetic Phenomena; Magnetics; Materials Testing; Mathematical models; Methylene Blue - chemistry; Oxygen - chemistry; Peroxides - chemistry; Peroxymonosulfate; Regeneration; Spectroscopy, Fourier Transform Infrared; Sulfate radical; Sulfates - chemistry; Surface chemistry; Water Pollutants, Chemical - analysis; Water Purification - methods; X-Ray Diffraction
• ISSN: 0304-3894; 1873-3336
• DOI: 10.1016/j.jhazmat.2014.10.042

[Display omitted] •Magnetic activated carbon composite (MACC) was synthesized.•MACC was used as peroxymonosulfate (PMS) activator and regenerable adsorbent.•Regeneration efficiency of MACC was quantified.•Kinetic model for regeneration process was proposed.•MACC surface chemistry change during reaction with PMS was studied. Magnetic activated carbon composite (CuFe2O4/AC, MACC) was prepared by a co-precipitation–calcination method. The MACC consisted of porous micro-particle morphology with homogeneously distributed CuFe2O4 and possessed high magnetic saturation moment (8.1emug−1). The performance of MACC was evaluated as catalyst and regenerable adsorbent via peroxymonosulfate (PMS, Oxone®) activation for methylene blue (MB) removal. Optimum CuFe2O4/AC w/w ratio was 1:1.5 giving excellent performance and can be reused for at least 3 cycles. The presence of common inorganic ions, namely Cl− and NO3− did not exert significant influence on MB degradation but humic acid decreased the MB degradation rate. As a regenerable adsorbent, negligible difference in regeneration efficiency was observed when a higher Oxone® dosage was employed but a better efficiency was obtained at a lower MACC loading. The factors hindering complete MACC regeneration are MB adsorption irreversibility and AC surface modification by PMS making it less favorable for subsequent MB adsorption. With an additional mild heat treatment (150°C) after regeneration, 82% of the active sites were successfully regenerated. A kinetic model incorporating simultaneous first-order desorption, second-order adsorption and pseudo-first order degradation processes was numerically-solved to describe the rate of regeneration. The regeneration rate increased linearly with increasing Oxone®:MACC ratio. The MACC could potentially serve as a catalyst for PMS activation and regenerable adsorbent.