Texture, local misorientation, grain boundary and recrystallization fraction in pipeline steels related to hydrogen induced cracking

• Published in: Materials science & engineering. A, Structural materials : properties, microstructure and processing Structural materials : properties, microstructure and processing, 2015-01, Vol.620, p.97-106
• Main Authors: Mohtadi-Bonab, M.A., Eskandari, M., Szpunar, J.A.
• Format: Article
• Language: English
• Subjects: Coincidence site lattice boundary; Crystallographic texture; Electron backscatter diffraction; Fracture mechanics; Grain boundaries; High strength low alloy steels; Kernel Average Misorientation; Orientation; Pipelines; Recrystallization; Structural steels; Texture
• ISSN: 0921-5093; 1873-4936
• DOI: 10.1016/j.msea.2014.10.009

In the present study, API X60 and X60SS pipeline steels were cathodically charged by hydrogen for 8h using 0.2M sulfuric acid and 3g/l ammonium thiocyanate. After charging, SEM observations showed that the hydrogen induced cracking (HIC) appeared at the center of cross section in the X60 specimen. However, HIC did not appear in the X60SS steel. Therefore, electron backscatter diffraction (EBSD) technique was used to analyze the center of cross section of as-received X60SS, X60 and HIC tested X60 specimens. The results showed that the HIC crack not only can propagate through 〈100〉||ND oriented grains but also its growth may happen in various orientations. In HIC tested X60 specimen, an accumulation of low angle grain boundaries around the crack path documented that full recrystallization was not achieved during hot rolling. Kernel Average Misorientaion (KAM) histogram illustrated that the deformation is more concentrated in as-received and HIC tested X60 specimens rather than in as-received X60SS specimen. Moreover, the concentration of coincidence site lattice (CSL) boundary in HIC tested X60 specimen was very low compared with other samples. The recrystallization area fraction in X60SS steel was very high. This high amount of recrystallization fraction with no stored energy is one of the main reasons for high HIC resistance of this steel to HIC. The orientation distribution function (ODF) of the recrystallized, substructured and deformed fractions in as-received X60SS and X60 steel showed relative close orientations in both as-received specimens.