Direct ortho-Thiolation of Arenes and Alkenes by Nickel Catalysis

The direct thiolation of arenes and alkenes with diaryl disulfides was developed by nickel catalysis. The reaction displayed exceptional compatibility with a wide range of functional groups to regioselectively give the diaryl sulfides and alkenyl sulfides in high yields.

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Bibliographic Details
Published in:Organic letters 2015-03, Vol.17 (5), p.1328-1331
Main Authors: Lin, Cong, Li, Danyang, Wang, Binjie, Yao, Jinzhong, Zhang, Yuhong
Format: Article
Language:English
Subjects:
Alkenes - chemistry
Catalysis
Molecular Structure
Nickel - chemistry
Stereoisomerism
Sulfhydryl Compounds - chemistry
Sulfides - chemistry
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Description
Summary:The direct thiolation of arenes and alkenes with diaryl disulfides was developed by nickel catalysis. The reaction displayed exceptional compatibility with a wide range of functional groups to regioselectively give the diaryl sulfides and alkenyl sulfides in high yields.
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.5b00337