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Spin-dependent charge transfer state design rules in organic photovoltaics

Charge transfer states play a crucial role in organic photovoltaics, mediating both photocurrent generation and recombination losses. In this work, we examine recombination losses as a function of the electron-hole spacing in fluorescent charge transfer states, including direct monitoring of both si...

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Bibliographic Details
Published in:Nature communications 2015-03, Vol.6 (1), p.6415-6415, Article 6415
Main Authors: Chang, Wendi, Congreve, Daniel N., Hontz, Eric, Bahlke, Matthias E., McMahon, David P., Reineke, Sebastian, Wu, Tony C., Bulović, Vladimir, Van Voorhis, Troy, Baldo, Marc A.
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Language:English
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Summary:Charge transfer states play a crucial role in organic photovoltaics, mediating both photocurrent generation and recombination losses. In this work, we examine recombination losses as a function of the electron-hole spacing in fluorescent charge transfer states, including direct monitoring of both singlet and triplet charge transfer state dynamics. Here we demonstrate that large donor–acceptor separations minimize back transfer from the charge transfer state to a low-lying triplet exciton ‘drain’ or the ground state by utilizing external pressure to modulate molecular spacing. The triplet drain quenches triplet charge transfer states that would otherwise be spin protected against recombination, and switches the most efficient origin of the photocurrent from triplet to singlet charge transfer states. Future organic solar cell designs should focus on raising the energy of triplet excitons to better utilize triplet charge transfer mediated photocurrent generation or increasing the donor–acceptor spacing to minimize recombination losses. An important source of loss in solar cells is the recombination of the photogenerated charge carriers before they are extracted from the device. Chang et al . now show that such recombination can be reduced in organic solar cells by increasing the separation between donors and acceptors.
ISSN:2041-1723
2041-1723
DOI:10.1038/ncomms7415