Facile Base-Mediated Redox Transformation: An Efficient Strategy for the Synthesis of α‑Acyloxyphosphoryl Compounds

An efficient one-pot synthesis of α-acyloxyphosphoryl compounds from aldehydes and hydrogen phosphoryl compounds has been developed using a facile base-mediated redox strategy. This redox transformation is applicable to synthesize a wide range of valuable α-acyloxyphosphoryl compounds with high atom...

Full description

Saved in:
Bibliographic Details
Published in:Organic letters 2014-12, Vol.16 (23), p.6152-6155
Main Authors: Zhao, Yalei, Chen, Tieqiao, Han, Daoqing, Zhao, Chang-Qiu, Han, Li-Biao
Format: Article
Language:English
Subjects:
Catalysis
Combinatorial Chemistry Techniques
Molecular Structure
Organophosphorus Compounds - chemical synthesis
Organophosphorus Compounds - chemistry
Oxidation-Reduction
Stereoisomerism
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:An efficient one-pot synthesis of α-acyloxyphosphoryl compounds from aldehydes and hydrogen phosphoryl compounds has been developed using a facile base-mediated redox strategy. This redox transformation is applicable to synthesize a wide range of valuable α-acyloxyphosphoryl compounds with high atom- and step-economic efficiency.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol503014f