Yb3+, Er3+ doped Y2O3 nanoparticles of different shapes prepared by self-propagating room temperature reaction method

• Published in: Ceramics international 2014-12, Vol.40 (10), p.16033-16039
• Main Authors: Lojpur, Vesna, Ahrenkiel, Scott P., Dramićanin, Miroslav D.
• Format: Article
• Language: English
• Subjects: Calcination; Emission; Excitation; Infrared; Nanoparticles; Rare earth; Roasting; Spectral emissivity; Synthesis; Up-conversion; Upconversion; Yttrium oxide
• ISSN: 0272-8842; 1873-3956
• DOI: 10.1016/j.ceramint.2014.07.139

In this report, a cost- and time-effective method for synthesis of Y2O3:Yb3+, Er3+ nanoparticles that exhibit up-conversion emission under infrared excitation is presented. The synthesis method is based on the self-propagating, room-temperature reaction between metal nitrates and sodium hydroxide, and a subsequent calcination process. Series of samples were prepared with calcinations at various temperatures (600°C, 800°C and 1100°C) for 1h, and also with different Yb3+–Er3+ ratios (10:1, 5:1 and 2:1). All calcined samples crystallized in a cubic bixbyite crystal phase with crystallite size from 12 to 44nm in diameter, for samples calcined at 600°C and 1100°C, respectively. Different nanoparticle morphologies were obtained after calcinations on different temperatures; at temperatures under 1100°C rod-like particles were obtained, while at 1100°C spherical particles were formed. In all samples up-conversion emissions and corresponding lifetimes were measured after excitation in room temperature at 978nm. The most intense emission originates from the characteristic intra-shell f–f electronic transitions of Er3+ ions: [2H9/2→4I15/2] in blue (407–420nm); [(2H11/2, 4S3/2)→4I15/2] green: 510–590nm; and [4F9/2→4I15/2] in red (640–720nm) spectral regions.