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Three coordination polymers constructed from bis(imidazol-l-yl-methyl)benzene: syntheses, structures, and third-order nonlinear optical properties
Three coordination polymers, {[Ni(H 2 O) 2 (bib) 2 ]-(H 2 BTA)·2H 2 O} n ( 1 ), {[Co 2 (bib) 2 (BTA)]·H 2 O} n ( 2 ), and {[Co 2 (bib) 2 (CA) 2 ]·H 2 O} n ( 3 ), (H 4 BTA = biphenyl-3,3′,4,4′-tetracarboxylic acid; bib = 1, 2-bis(imidazol-l-yl-methyl)benzene; H 2 CA = camphanic acid), have been synth...
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Published in: | Transition metal chemistry (Weinheim) 2015-02, Vol.40 (1), p.11-19 |
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creator | Zhao, Ning Deng, Yue-E. Liu, Ping An, Cai-Xia Wang, Tian-Xi Lian, Zhao-Xun |
description | Three coordination polymers, {[Ni(H
2
O)
2
(bib)
2
]-(H
2
BTA)·2H
2
O}
n
(
1
), {[Co
2
(bib)
2
(BTA)]·H
2
O}
n
(
2
), and {[Co
2
(bib)
2
(CA)
2
]·H
2
O}
n
(
3
), (H
4
BTA = biphenyl-3,3′,4,4′-tetracarboxylic acid; bib = 1, 2-bis(imidazol-l-yl-methyl)benzene; H
2
CA = camphanic acid), have been synthesized under hydrothermal conditions. In complex
1
, bib serves a bridging ligand to link two Ni(II) atoms into an infinite joint-like chain. In
2
, binuclear units are connected by BTA and bib ligands to form 2-D sheets. In
3
, each Ni(II) atom is coordinated with two bib ligands to give a 22-membered ring, which is further linked by CA ligands to form a ladder-like chain. The third-order nonlinear optical (NLO) properties of the complexes were determined by Z-scan technique in DMSO solution. All three complexes exhibit strong third-order NLO absorption with absorptive coefficients β(MKS) 1.44 × 10
−10
m W
−1
for
1
, 1.68 × 10
−10
m W
−1
for
2
, and −6.31 × 10
−10
m W
−1
for
3
, respectively, of which compound
3
shows saturable absorption. The third-order NLO susceptibilities |
χ
(3)
| were calculated as 0.32 × 10
−10
for
1
, 0.37 × 10
−10
for
2
, and 1.39 × 10
−10
esu for
3
, while the hyperpolarizabilities
γ
′ are 9.95 × 10
−29
for
1
, 5.85 × 10
−29
for
2
and 4.64 × 10
−28
esu for
3
, respectively. |
doi_str_mv | 10.1007/s11243-014-9884-z |
format | article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1669855046</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1669855046</sourcerecordid><originalsourceid>FETCH-LOGICAL-c419t-3871a4da74a942e42cdeca68dc34b943347484a3616398bc5c8bc9d72a68790b3</originalsourceid><addsrcrecordid>eNp1kc2KFTEQhYMoeB19AHcBNyMYzV93ut3JMP7AgJsR3IV0UtebIZ20SXrR9zF8YnNpFyK4qSqK79QpOAi9ZPQto1S9K4xxKQhlkozDIMn5ETqwTnEyUvb9MTpQISmRfOieomelPFBKO67kAf26P2UAbFPKzkdTfYp4SWGbIZe2jaXm1VZw-JjTjCdfrv3snTmnQALZApmhnrbweoJ4hgjvcdliPUGB8gbv0jVfZhMdriefHWk-kHFMMfgIJuO0VG9NwEtOC-TqoTxHT44mFHjxp1-hbx9v728-k7uvn77cfLgjVrKxEjEoZqQzSppRcpDcOrCmH5wVchqlEFLJQRrRs16Mw2Q728roFG-MGukkrtD1frdZ_1yhVD37YiEEEyGtRbO-H4euo7Jv6Kt_0Ie05ti-a5RUginV8UaxnbI5lZLhqJfsZ5M3zai-pKT3lHRLSV9S0uem4bumNDb-gPzX5f-KfgN1eJkX</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1647317752</pqid></control><display><type>article</type><title>Three coordination polymers constructed from bis(imidazol-l-yl-methyl)benzene: syntheses, structures, and third-order nonlinear optical properties</title><source>Springer Link</source><creator>Zhao, Ning ; Deng, Yue-E. ; Liu, Ping ; An, Cai-Xia ; Wang, Tian-Xi ; Lian, Zhao-Xun</creator><creatorcontrib>Zhao, Ning ; Deng, Yue-E. ; Liu, Ping ; An, Cai-Xia ; Wang, Tian-Xi ; Lian, Zhao-Xun</creatorcontrib><description>Three coordination polymers, {[Ni(H
2
O)
2
(bib)
2
]-(H
2
BTA)·2H
2
O}
n
(
1
), {[Co
2
(bib)
2
(BTA)]·H
2
O}
n
(
2
), and {[Co
2
(bib)
2
(CA)
2
]·H
2
O}
n
(
3
), (H
4
BTA = biphenyl-3,3′,4,4′-tetracarboxylic acid; bib = 1, 2-bis(imidazol-l-yl-methyl)benzene; H
2
CA = camphanic acid), have been synthesized under hydrothermal conditions. In complex
1
, bib serves a bridging ligand to link two Ni(II) atoms into an infinite joint-like chain. In
2
, binuclear units are connected by BTA and bib ligands to form 2-D sheets. In
3
, each Ni(II) atom is coordinated with two bib ligands to give a 22-membered ring, which is further linked by CA ligands to form a ladder-like chain. The third-order nonlinear optical (NLO) properties of the complexes were determined by Z-scan technique in DMSO solution. All three complexes exhibit strong third-order NLO absorption with absorptive coefficients β(MKS) 1.44 × 10
−10
m W
−1
for
1
, 1.68 × 10
−10
m W
−1
for
2
, and −6.31 × 10
−10
m W
−1
for
3
, respectively, of which compound
3
shows saturable absorption. The third-order NLO susceptibilities |
χ
(3)
| were calculated as 0.32 × 10
−10
for
1
, 0.37 × 10
−10
for
2
, and 1.39 × 10
−10
esu for
3
, while the hyperpolarizabilities
γ
′ are 9.95 × 10
−29
for
1
, 5.85 × 10
−29
for
2
and 4.64 × 10
−28
esu for
3
, respectively.</description><identifier>ISSN: 0340-4285</identifier><identifier>EISSN: 1572-901X</identifier><identifier>DOI: 10.1007/s11243-014-9884-z</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Absorptivity ; Catalysis ; Chains ; Chemistry ; Chemistry and Materials Science ; Construction ; Coordination polymers ; Inorganic Chemistry ; Ligands ; Links ; Mathematical analysis ; Nonlinearity ; Optical properties ; Organometallic Chemistry ; Physical Chemistry</subject><ispartof>Transition metal chemistry (Weinheim), 2015-02, Vol.40 (1), p.11-19</ispartof><rights>Springer International Publishing Switzerland 2014</rights><rights>Springer International Publishing Switzerland 2015</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c419t-3871a4da74a942e42cdeca68dc34b943347484a3616398bc5c8bc9d72a68790b3</citedby><cites>FETCH-LOGICAL-c419t-3871a4da74a942e42cdeca68dc34b943347484a3616398bc5c8bc9d72a68790b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Zhao, Ning</creatorcontrib><creatorcontrib>Deng, Yue-E.</creatorcontrib><creatorcontrib>Liu, Ping</creatorcontrib><creatorcontrib>An, Cai-Xia</creatorcontrib><creatorcontrib>Wang, Tian-Xi</creatorcontrib><creatorcontrib>Lian, Zhao-Xun</creatorcontrib><title>Three coordination polymers constructed from bis(imidazol-l-yl-methyl)benzene: syntheses, structures, and third-order nonlinear optical properties</title><title>Transition metal chemistry (Weinheim)</title><addtitle>Transition Met Chem</addtitle><description>Three coordination polymers, {[Ni(H
2
O)
2
(bib)
2
]-(H
2
BTA)·2H
2
O}
n
(
1
), {[Co
2
(bib)
2
(BTA)]·H
2
O}
n
(
2
), and {[Co
2
(bib)
2
(CA)
2
]·H
2
O}
n
(
3
), (H
4
BTA = biphenyl-3,3′,4,4′-tetracarboxylic acid; bib = 1, 2-bis(imidazol-l-yl-methyl)benzene; H
2
CA = camphanic acid), have been synthesized under hydrothermal conditions. In complex
1
, bib serves a bridging ligand to link two Ni(II) atoms into an infinite joint-like chain. In
2
, binuclear units are connected by BTA and bib ligands to form 2-D sheets. In
3
, each Ni(II) atom is coordinated with two bib ligands to give a 22-membered ring, which is further linked by CA ligands to form a ladder-like chain. The third-order nonlinear optical (NLO) properties of the complexes were determined by Z-scan technique in DMSO solution. All three complexes exhibit strong third-order NLO absorption with absorptive coefficients β(MKS) 1.44 × 10
−10
m W
−1
for
1
, 1.68 × 10
−10
m W
−1
for
2
, and −6.31 × 10
−10
m W
−1
for
3
, respectively, of which compound
3
shows saturable absorption. The third-order NLO susceptibilities |
χ
(3)
| were calculated as 0.32 × 10
−10
for
1
, 0.37 × 10
−10
for
2
, and 1.39 × 10
−10
esu for
3
, while the hyperpolarizabilities
γ
′ are 9.95 × 10
−29
for
1
, 5.85 × 10
−29
for
2
and 4.64 × 10
−28
esu for
3
, respectively.</description><subject>Absorptivity</subject><subject>Catalysis</subject><subject>Chains</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Construction</subject><subject>Coordination polymers</subject><subject>Inorganic Chemistry</subject><subject>Ligands</subject><subject>Links</subject><subject>Mathematical analysis</subject><subject>Nonlinearity</subject><subject>Optical properties</subject><subject>Organometallic Chemistry</subject><subject>Physical Chemistry</subject><issn>0340-4285</issn><issn>1572-901X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp1kc2KFTEQhYMoeB19AHcBNyMYzV93ut3JMP7AgJsR3IV0UtebIZ20SXrR9zF8YnNpFyK4qSqK79QpOAi9ZPQto1S9K4xxKQhlkozDIMn5ETqwTnEyUvb9MTpQISmRfOieomelPFBKO67kAf26P2UAbFPKzkdTfYp4SWGbIZe2jaXm1VZw-JjTjCdfrv3snTmnQALZApmhnrbweoJ4hgjvcdliPUGB8gbv0jVfZhMdriefHWk-kHFMMfgIJuO0VG9NwEtOC-TqoTxHT44mFHjxp1-hbx9v728-k7uvn77cfLgjVrKxEjEoZqQzSppRcpDcOrCmH5wVchqlEFLJQRrRs16Mw2Q728roFG-MGukkrtD1frdZ_1yhVD37YiEEEyGtRbO-H4euo7Jv6Kt_0Ie05ti-a5RUginV8UaxnbI5lZLhqJfsZ5M3zai-pKT3lHRLSV9S0uem4bumNDb-gPzX5f-KfgN1eJkX</recordid><startdate>20150201</startdate><enddate>20150201</enddate><creator>Zhao, Ning</creator><creator>Deng, Yue-E.</creator><creator>Liu, Ping</creator><creator>An, Cai-Xia</creator><creator>Wang, Tian-Xi</creator><creator>Lian, Zhao-Xun</creator><general>Springer International Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7SP</scope><scope>7SR</scope><scope>L7M</scope></search><sort><creationdate>20150201</creationdate><title>Three coordination polymers constructed from bis(imidazol-l-yl-methyl)benzene: syntheses, structures, and third-order nonlinear optical properties</title><author>Zhao, Ning ; Deng, Yue-E. ; Liu, Ping ; An, Cai-Xia ; Wang, Tian-Xi ; Lian, Zhao-Xun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c419t-3871a4da74a942e42cdeca68dc34b943347484a3616398bc5c8bc9d72a68790b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Absorptivity</topic><topic>Catalysis</topic><topic>Chains</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Construction</topic><topic>Coordination polymers</topic><topic>Inorganic Chemistry</topic><topic>Ligands</topic><topic>Links</topic><topic>Mathematical analysis</topic><topic>Nonlinearity</topic><topic>Optical properties</topic><topic>Organometallic Chemistry</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhao, Ning</creatorcontrib><creatorcontrib>Deng, Yue-E.</creatorcontrib><creatorcontrib>Liu, Ping</creatorcontrib><creatorcontrib>An, Cai-Xia</creatorcontrib><creatorcontrib>Wang, Tian-Xi</creatorcontrib><creatorcontrib>Lian, Zhao-Xun</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Transition metal chemistry (Weinheim)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhao, Ning</au><au>Deng, Yue-E.</au><au>Liu, Ping</au><au>An, Cai-Xia</au><au>Wang, Tian-Xi</au><au>Lian, Zhao-Xun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Three coordination polymers constructed from bis(imidazol-l-yl-methyl)benzene: syntheses, structures, and third-order nonlinear optical properties</atitle><jtitle>Transition metal chemistry (Weinheim)</jtitle><stitle>Transition Met Chem</stitle><date>2015-02-01</date><risdate>2015</risdate><volume>40</volume><issue>1</issue><spage>11</spage><epage>19</epage><pages>11-19</pages><issn>0340-4285</issn><eissn>1572-901X</eissn><abstract>Three coordination polymers, {[Ni(H
2
O)
2
(bib)
2
]-(H
2
BTA)·2H
2
O}
n
(
1
), {[Co
2
(bib)
2
(BTA)]·H
2
O}
n
(
2
), and {[Co
2
(bib)
2
(CA)
2
]·H
2
O}
n
(
3
), (H
4
BTA = biphenyl-3,3′,4,4′-tetracarboxylic acid; bib = 1, 2-bis(imidazol-l-yl-methyl)benzene; H
2
CA = camphanic acid), have been synthesized under hydrothermal conditions. In complex
1
, bib serves a bridging ligand to link two Ni(II) atoms into an infinite joint-like chain. In
2
, binuclear units are connected by BTA and bib ligands to form 2-D sheets. In
3
, each Ni(II) atom is coordinated with two bib ligands to give a 22-membered ring, which is further linked by CA ligands to form a ladder-like chain. The third-order nonlinear optical (NLO) properties of the complexes were determined by Z-scan technique in DMSO solution. All three complexes exhibit strong third-order NLO absorption with absorptive coefficients β(MKS) 1.44 × 10
−10
m W
−1
for
1
, 1.68 × 10
−10
m W
−1
for
2
, and −6.31 × 10
−10
m W
−1
for
3
, respectively, of which compound
3
shows saturable absorption. The third-order NLO susceptibilities |
χ
(3)
| were calculated as 0.32 × 10
−10
for
1
, 0.37 × 10
−10
for
2
, and 1.39 × 10
−10
esu for
3
, while the hyperpolarizabilities
γ
′ are 9.95 × 10
−29
for
1
, 5.85 × 10
−29
for
2
and 4.64 × 10
−28
esu for
3
, respectively.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s11243-014-9884-z</doi><tpages>9</tpages></addata></record> |
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subjects | Absorptivity Catalysis Chains Chemistry Chemistry and Materials Science Construction Coordination polymers Inorganic Chemistry Ligands Links Mathematical analysis Nonlinearity Optical properties Organometallic Chemistry Physical Chemistry |
title | Three coordination polymers constructed from bis(imidazol-l-yl-methyl)benzene: syntheses, structures, and third-order nonlinear optical properties |
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