Loading…

Three coordination polymers constructed from bis(imidazol-l-yl-methyl)benzene: syntheses, structures, and third-order nonlinear optical properties

Three coordination polymers, {[Ni(H 2 O) 2 (bib) 2 ]-(H 2 BTA)·2H 2 O} n ( 1 ), {[Co 2 (bib) 2 (BTA)]·H 2 O} n ( 2 ), and {[Co 2 (bib) 2 (CA) 2 ]·H 2 O} n ( 3 ), (H 4 BTA = biphenyl-3,3′,4,4′-tetracarboxylic acid; bib = 1, 2-bis(imidazol-l-yl-methyl)benzene; H 2 CA = camphanic acid), have been synth...

Full description

Saved in:
Bibliographic Details
Published in:Transition metal chemistry (Weinheim) 2015-02, Vol.40 (1), p.11-19
Main Authors: Zhao, Ning, Deng, Yue-E., Liu, Ping, An, Cai-Xia, Wang, Tian-Xi, Lian, Zhao-Xun
Format: Article
Language:English
Subjects:
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c419t-3871a4da74a942e42cdeca68dc34b943347484a3616398bc5c8bc9d72a68790b3
cites cdi_FETCH-LOGICAL-c419t-3871a4da74a942e42cdeca68dc34b943347484a3616398bc5c8bc9d72a68790b3
container_end_page 19
container_issue 1
container_start_page 11
container_title Transition metal chemistry (Weinheim)
container_volume 40
creator Zhao, Ning
Deng, Yue-E.
Liu, Ping
An, Cai-Xia
Wang, Tian-Xi
Lian, Zhao-Xun
description Three coordination polymers, {[Ni(H 2 O) 2 (bib) 2 ]-(H 2 BTA)·2H 2 O} n ( 1 ), {[Co 2 (bib) 2 (BTA)]·H 2 O} n ( 2 ), and {[Co 2 (bib) 2 (CA) 2 ]·H 2 O} n ( 3 ), (H 4 BTA = biphenyl-3,3′,4,4′-tetracarboxylic acid; bib = 1, 2-bis(imidazol-l-yl-methyl)benzene; H 2 CA = camphanic acid), have been synthesized under hydrothermal conditions. In complex 1 , bib serves a bridging ligand to link two Ni(II) atoms into an infinite joint-like chain. In 2 , binuclear units are connected by BTA and bib ligands to form 2-D sheets. In 3 , each Ni(II) atom is coordinated with two bib ligands to give a 22-membered ring, which is further linked by CA ligands to form a ladder-like chain. The third-order nonlinear optical (NLO) properties of the complexes were determined by Z-scan technique in DMSO solution. All three complexes exhibit strong third-order NLO absorption with absorptive coefficients β(MKS) 1.44 × 10 −10  m W −1 for 1 , 1.68 × 10 −10  m W −1 for 2 , and −6.31 × 10 −10  m W −1 for 3 , respectively, of which compound 3 shows saturable absorption. The third-order NLO susceptibilities | χ (3) | were calculated as 0.32 × 10 −10 for 1 , 0.37 × 10 −10 for 2 , and 1.39 × 10 −10  esu for 3 , while the hyperpolarizabilities γ ′ are 9.95 × 10 −29 for 1 , 5.85 × 10 −29 for 2 and 4.64 × 10 −28  esu for 3 , respectively.
doi_str_mv 10.1007/s11243-014-9884-z
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1669855046</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1669855046</sourcerecordid><originalsourceid>FETCH-LOGICAL-c419t-3871a4da74a942e42cdeca68dc34b943347484a3616398bc5c8bc9d72a68790b3</originalsourceid><addsrcrecordid>eNp1kc2KFTEQhYMoeB19AHcBNyMYzV93ut3JMP7AgJsR3IV0UtebIZ20SXrR9zF8YnNpFyK4qSqK79QpOAi9ZPQto1S9K4xxKQhlkozDIMn5ETqwTnEyUvb9MTpQISmRfOieomelPFBKO67kAf26P2UAbFPKzkdTfYp4SWGbIZe2jaXm1VZw-JjTjCdfrv3snTmnQALZApmhnrbweoJ4hgjvcdliPUGB8gbv0jVfZhMdriefHWk-kHFMMfgIJuO0VG9NwEtOC-TqoTxHT44mFHjxp1-hbx9v728-k7uvn77cfLgjVrKxEjEoZqQzSppRcpDcOrCmH5wVchqlEFLJQRrRs16Mw2Q728roFG-MGukkrtD1frdZ_1yhVD37YiEEEyGtRbO-H4euo7Jv6Kt_0Ie05ti-a5RUginV8UaxnbI5lZLhqJfsZ5M3zai-pKT3lHRLSV9S0uem4bumNDb-gPzX5f-KfgN1eJkX</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1647317752</pqid></control><display><type>article</type><title>Three coordination polymers constructed from bis(imidazol-l-yl-methyl)benzene: syntheses, structures, and third-order nonlinear optical properties</title><source>Springer Link</source><creator>Zhao, Ning ; Deng, Yue-E. ; Liu, Ping ; An, Cai-Xia ; Wang, Tian-Xi ; Lian, Zhao-Xun</creator><creatorcontrib>Zhao, Ning ; Deng, Yue-E. ; Liu, Ping ; An, Cai-Xia ; Wang, Tian-Xi ; Lian, Zhao-Xun</creatorcontrib><description>Three coordination polymers, {[Ni(H 2 O) 2 (bib) 2 ]-(H 2 BTA)·2H 2 O} n ( 1 ), {[Co 2 (bib) 2 (BTA)]·H 2 O} n ( 2 ), and {[Co 2 (bib) 2 (CA) 2 ]·H 2 O} n ( 3 ), (H 4 BTA = biphenyl-3,3′,4,4′-tetracarboxylic acid; bib = 1, 2-bis(imidazol-l-yl-methyl)benzene; H 2 CA = camphanic acid), have been synthesized under hydrothermal conditions. In complex 1 , bib serves a bridging ligand to link two Ni(II) atoms into an infinite joint-like chain. In 2 , binuclear units are connected by BTA and bib ligands to form 2-D sheets. In 3 , each Ni(II) atom is coordinated with two bib ligands to give a 22-membered ring, which is further linked by CA ligands to form a ladder-like chain. The third-order nonlinear optical (NLO) properties of the complexes were determined by Z-scan technique in DMSO solution. All three complexes exhibit strong third-order NLO absorption with absorptive coefficients β(MKS) 1.44 × 10 −10  m W −1 for 1 , 1.68 × 10 −10  m W −1 for 2 , and −6.31 × 10 −10  m W −1 for 3 , respectively, of which compound 3 shows saturable absorption. The third-order NLO susceptibilities | χ (3) | were calculated as 0.32 × 10 −10 for 1 , 0.37 × 10 −10 for 2 , and 1.39 × 10 −10  esu for 3 , while the hyperpolarizabilities γ ′ are 9.95 × 10 −29 for 1 , 5.85 × 10 −29 for 2 and 4.64 × 10 −28  esu for 3 , respectively.</description><identifier>ISSN: 0340-4285</identifier><identifier>EISSN: 1572-901X</identifier><identifier>DOI: 10.1007/s11243-014-9884-z</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Absorptivity ; Catalysis ; Chains ; Chemistry ; Chemistry and Materials Science ; Construction ; Coordination polymers ; Inorganic Chemistry ; Ligands ; Links ; Mathematical analysis ; Nonlinearity ; Optical properties ; Organometallic Chemistry ; Physical Chemistry</subject><ispartof>Transition metal chemistry (Weinheim), 2015-02, Vol.40 (1), p.11-19</ispartof><rights>Springer International Publishing Switzerland 2014</rights><rights>Springer International Publishing Switzerland 2015</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c419t-3871a4da74a942e42cdeca68dc34b943347484a3616398bc5c8bc9d72a68790b3</citedby><cites>FETCH-LOGICAL-c419t-3871a4da74a942e42cdeca68dc34b943347484a3616398bc5c8bc9d72a68790b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Zhao, Ning</creatorcontrib><creatorcontrib>Deng, Yue-E.</creatorcontrib><creatorcontrib>Liu, Ping</creatorcontrib><creatorcontrib>An, Cai-Xia</creatorcontrib><creatorcontrib>Wang, Tian-Xi</creatorcontrib><creatorcontrib>Lian, Zhao-Xun</creatorcontrib><title>Three coordination polymers constructed from bis(imidazol-l-yl-methyl)benzene: syntheses, structures, and third-order nonlinear optical properties</title><title>Transition metal chemistry (Weinheim)</title><addtitle>Transition Met Chem</addtitle><description>Three coordination polymers, {[Ni(H 2 O) 2 (bib) 2 ]-(H 2 BTA)·2H 2 O} n ( 1 ), {[Co 2 (bib) 2 (BTA)]·H 2 O} n ( 2 ), and {[Co 2 (bib) 2 (CA) 2 ]·H 2 O} n ( 3 ), (H 4 BTA = biphenyl-3,3′,4,4′-tetracarboxylic acid; bib = 1, 2-bis(imidazol-l-yl-methyl)benzene; H 2 CA = camphanic acid), have been synthesized under hydrothermal conditions. In complex 1 , bib serves a bridging ligand to link two Ni(II) atoms into an infinite joint-like chain. In 2 , binuclear units are connected by BTA and bib ligands to form 2-D sheets. In 3 , each Ni(II) atom is coordinated with two bib ligands to give a 22-membered ring, which is further linked by CA ligands to form a ladder-like chain. The third-order nonlinear optical (NLO) properties of the complexes were determined by Z-scan technique in DMSO solution. All three complexes exhibit strong third-order NLO absorption with absorptive coefficients β(MKS) 1.44 × 10 −10  m W −1 for 1 , 1.68 × 10 −10  m W −1 for 2 , and −6.31 × 10 −10  m W −1 for 3 , respectively, of which compound 3 shows saturable absorption. The third-order NLO susceptibilities | χ (3) | were calculated as 0.32 × 10 −10 for 1 , 0.37 × 10 −10 for 2 , and 1.39 × 10 −10  esu for 3 , while the hyperpolarizabilities γ ′ are 9.95 × 10 −29 for 1 , 5.85 × 10 −29 for 2 and 4.64 × 10 −28  esu for 3 , respectively.</description><subject>Absorptivity</subject><subject>Catalysis</subject><subject>Chains</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Construction</subject><subject>Coordination polymers</subject><subject>Inorganic Chemistry</subject><subject>Ligands</subject><subject>Links</subject><subject>Mathematical analysis</subject><subject>Nonlinearity</subject><subject>Optical properties</subject><subject>Organometallic Chemistry</subject><subject>Physical Chemistry</subject><issn>0340-4285</issn><issn>1572-901X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp1kc2KFTEQhYMoeB19AHcBNyMYzV93ut3JMP7AgJsR3IV0UtebIZ20SXrR9zF8YnNpFyK4qSqK79QpOAi9ZPQto1S9K4xxKQhlkozDIMn5ETqwTnEyUvb9MTpQISmRfOieomelPFBKO67kAf26P2UAbFPKzkdTfYp4SWGbIZe2jaXm1VZw-JjTjCdfrv3snTmnQALZApmhnrbweoJ4hgjvcdliPUGB8gbv0jVfZhMdriefHWk-kHFMMfgIJuO0VG9NwEtOC-TqoTxHT44mFHjxp1-hbx9v728-k7uvn77cfLgjVrKxEjEoZqQzSppRcpDcOrCmH5wVchqlEFLJQRrRs16Mw2Q728roFG-MGukkrtD1frdZ_1yhVD37YiEEEyGtRbO-H4euo7Jv6Kt_0Ie05ti-a5RUginV8UaxnbI5lZLhqJfsZ5M3zai-pKT3lHRLSV9S0uem4bumNDb-gPzX5f-KfgN1eJkX</recordid><startdate>20150201</startdate><enddate>20150201</enddate><creator>Zhao, Ning</creator><creator>Deng, Yue-E.</creator><creator>Liu, Ping</creator><creator>An, Cai-Xia</creator><creator>Wang, Tian-Xi</creator><creator>Lian, Zhao-Xun</creator><general>Springer International Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7SP</scope><scope>7SR</scope><scope>L7M</scope></search><sort><creationdate>20150201</creationdate><title>Three coordination polymers constructed from bis(imidazol-l-yl-methyl)benzene: syntheses, structures, and third-order nonlinear optical properties</title><author>Zhao, Ning ; Deng, Yue-E. ; Liu, Ping ; An, Cai-Xia ; Wang, Tian-Xi ; Lian, Zhao-Xun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c419t-3871a4da74a942e42cdeca68dc34b943347484a3616398bc5c8bc9d72a68790b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Absorptivity</topic><topic>Catalysis</topic><topic>Chains</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Construction</topic><topic>Coordination polymers</topic><topic>Inorganic Chemistry</topic><topic>Ligands</topic><topic>Links</topic><topic>Mathematical analysis</topic><topic>Nonlinearity</topic><topic>Optical properties</topic><topic>Organometallic Chemistry</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhao, Ning</creatorcontrib><creatorcontrib>Deng, Yue-E.</creatorcontrib><creatorcontrib>Liu, Ping</creatorcontrib><creatorcontrib>An, Cai-Xia</creatorcontrib><creatorcontrib>Wang, Tian-Xi</creatorcontrib><creatorcontrib>Lian, Zhao-Xun</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Electronics &amp; Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Transition metal chemistry (Weinheim)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhao, Ning</au><au>Deng, Yue-E.</au><au>Liu, Ping</au><au>An, Cai-Xia</au><au>Wang, Tian-Xi</au><au>Lian, Zhao-Xun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Three coordination polymers constructed from bis(imidazol-l-yl-methyl)benzene: syntheses, structures, and third-order nonlinear optical properties</atitle><jtitle>Transition metal chemistry (Weinheim)</jtitle><stitle>Transition Met Chem</stitle><date>2015-02-01</date><risdate>2015</risdate><volume>40</volume><issue>1</issue><spage>11</spage><epage>19</epage><pages>11-19</pages><issn>0340-4285</issn><eissn>1572-901X</eissn><abstract>Three coordination polymers, {[Ni(H 2 O) 2 (bib) 2 ]-(H 2 BTA)·2H 2 O} n ( 1 ), {[Co 2 (bib) 2 (BTA)]·H 2 O} n ( 2 ), and {[Co 2 (bib) 2 (CA) 2 ]·H 2 O} n ( 3 ), (H 4 BTA = biphenyl-3,3′,4,4′-tetracarboxylic acid; bib = 1, 2-bis(imidazol-l-yl-methyl)benzene; H 2 CA = camphanic acid), have been synthesized under hydrothermal conditions. In complex 1 , bib serves a bridging ligand to link two Ni(II) atoms into an infinite joint-like chain. In 2 , binuclear units are connected by BTA and bib ligands to form 2-D sheets. In 3 , each Ni(II) atom is coordinated with two bib ligands to give a 22-membered ring, which is further linked by CA ligands to form a ladder-like chain. The third-order nonlinear optical (NLO) properties of the complexes were determined by Z-scan technique in DMSO solution. All three complexes exhibit strong third-order NLO absorption with absorptive coefficients β(MKS) 1.44 × 10 −10  m W −1 for 1 , 1.68 × 10 −10  m W −1 for 2 , and −6.31 × 10 −10  m W −1 for 3 , respectively, of which compound 3 shows saturable absorption. The third-order NLO susceptibilities | χ (3) | were calculated as 0.32 × 10 −10 for 1 , 0.37 × 10 −10 for 2 , and 1.39 × 10 −10  esu for 3 , while the hyperpolarizabilities γ ′ are 9.95 × 10 −29 for 1 , 5.85 × 10 −29 for 2 and 4.64 × 10 −28  esu for 3 , respectively.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s11243-014-9884-z</doi><tpages>9</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0340-4285
ispartof Transition metal chemistry (Weinheim), 2015-02, Vol.40 (1), p.11-19
issn 0340-4285
1572-901X
language eng
recordid cdi_proquest_miscellaneous_1669855046
source Springer Link
subjects Absorptivity
Catalysis
Chains
Chemistry
Chemistry and Materials Science
Construction
Coordination polymers
Inorganic Chemistry
Ligands
Links
Mathematical analysis
Nonlinearity
Optical properties
Organometallic Chemistry
Physical Chemistry
title Three coordination polymers constructed from bis(imidazol-l-yl-methyl)benzene: syntheses, structures, and third-order nonlinear optical properties
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-05T05%3A14%3A49IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Three%20coordination%20polymers%20constructed%20from%20bis(imidazol-l-yl-methyl)benzene:%20syntheses,%20structures,%20and%20third-order%20nonlinear%20optical%20properties&rft.jtitle=Transition%20metal%20chemistry%20(Weinheim)&rft.au=Zhao,%20Ning&rft.date=2015-02-01&rft.volume=40&rft.issue=1&rft.spage=11&rft.epage=19&rft.pages=11-19&rft.issn=0340-4285&rft.eissn=1572-901X&rft_id=info:doi/10.1007/s11243-014-9884-z&rft_dat=%3Cproquest_cross%3E1669855046%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c419t-3871a4da74a942e42cdeca68dc34b943347484a3616398bc5c8bc9d72a68790b3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1647317752&rft_id=info:pmid/&rfr_iscdi=true