Effect of modified starch and nanoclay particles on biodegradability and mechanical properties of cross-linked poly lactic acid

•Full green cross-linked PLA/MTPS/MMT nanocomposite was prepared.•Modified thermoplastic starch was more compatible with PLA.•Nanoclay did not affect cross-linked PLA gel fraction but improved tensile strength.•By the addition of MTPS and nanoclay, biodegradability of composites was improved. Mechan...

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Bibliographic Details
Published in:Carbohydrate polymers 2015-06, Vol.124, p.237-244
Main Authors: Shayan, M., Azizi, H., Ghasemi, I., Karrabi, M.
Format: Article
Language:English
Subjects:
Bentonite - chemistry
Benzyl Compounds - chemistry
Biopolymers
Chemical crosslinking
Lactic Acid - chemistry
Maleic Anhydrides - chemistry
Nanocomposite
Nanocomposites - chemistry
Poly(lactic acid)
Polyesters
Polymers - chemistry
Starch - chemistry
Tensile Strength
Thermoplastic starch
Triazines - chemistry
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Summary:•Full green cross-linked PLA/MTPS/MMT nanocomposite was prepared.•Modified thermoplastic starch was more compatible with PLA.•Nanoclay did not affect cross-linked PLA gel fraction but improved tensile strength.•By the addition of MTPS and nanoclay, biodegradability of composites was improved. Mechanical properties and biodegradation of cross-linked poly(lactic acid) (PLA)/maleated thermoplastic starch (MTPS)/montmorillonite (MMT) nanocomposite were studied. Crosslinking was carried out by adding di-cumyl peroxide (DCP) in the presence of triallyl isocyanurate (TAIC) as coagent. At first, MTPS was prepared by grafting maleic anhydride (MA) to thermoplastic starch in internal mixer. Experimental design was performed by using Box–Behnken method at three variables: MTPS, nanoclay and TAIC at three levels. Results showed that increasing TAIC amount substantially increased the gel fraction, enhanced tensile strength, and caused a decrease in elongation at break. Biodegradation was prevented by increasing TAIC amount in nanocomposite. Increasing MTPS amount caused a slight increase in gel fraction and decreased the tensile strength of nanocomposite. Also, MTPS could increase the elongation at break of nanocomposite and improve the biodegradation. Nanoclay had no effect on the gel fraction, but it improved tensile strength.
ISSN:0144-8617
1879-1344
DOI:10.1016/j.carbpol.2015.02.001