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Mn2FeWO6: A New Ni3TeO6-Type Polar and Magnetic Oxide

Mn2+2Fe2+W6+O6, a new polar magnetic phase, adopts the corundum‐derived Ni3TeO6‐type structure with large spontaneous polarization (PS) of 67.8 μC cm−2, complex antiferromagnetic order below ≈75 K, and field‐induced first‐order transition to a ferrimagnetic phase below ≈30 K. First‐principles calcul...

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Bibliographic Details
Published in:Advanced materials (Weinheim) 2015-04, Vol.27 (13), p.2177-2181
Main Authors: Li, Man-Rong, Croft, Mark, Stephens, Peter W., Ye, Meng, Vanderbilt, David, Retuerto, Maria, Deng, Zheng, Grams, Christoph P., Hemberger, Joachim, Hadermann, Joke, Li, Wen-Min, Jin, Chang-Qing, Saouma, Felix O., Jang, Joon I., Akamatsu, Hirofumi, Gopalan, Venkatraman, Walker, David, Greenblatt, Martha
Format: Article
Language:English
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Summary:Mn2+2Fe2+W6+O6, a new polar magnetic phase, adopts the corundum‐derived Ni3TeO6‐type structure with large spontaneous polarization (PS) of 67.8 μC cm−2, complex antiferromagnetic order below ≈75 K, and field‐induced first‐order transition to a ferrimagnetic phase below ≈30 K. First‐principles calculations predict a ferrimagnetic (udu) ground state, optimal switching path along the c‐axis, and transition to a lower energy udu–udd magnetic double cell.
ISSN:0935-9648
1521-4095
DOI:10.1002/adma.201405244