Zinc–zinc bonded decamethyldizincocene Zn2(η5-C5Me5)2 as catalyst for the inter- and intramolecular hydroamination reaction

The Zn-Zn bonded compound [([small eta]5-Cp*)2Zn2] was investigated as catalyst for the inter- and intramolecular hydroamination reaction. High reaction rates under mild conditions were observed. This is the first application of a Zn-Zn bonded compound as catalyst.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2011-01, Vol.47 (29), p.8280-8282
Main Authors: Lühl, Anja, Pada Nayek, Hari, Blechert, Siegfried, Roesky, Peter W.
Format: Article
Language:English
Subjects:
Bonding
Catalysts
Zinc
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Summary:The Zn-Zn bonded compound [([small eta]5-Cp*)2Zn2] was investigated as catalyst for the inter- and intramolecular hydroamination reaction. High reaction rates under mild conditions were observed. This is the first application of a Zn-Zn bonded compound as catalyst.
ISSN:1359-7345
1364-548X
DOI:10.1039/c1cc12461g