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Film processability and properties of polycaprolactone/thermoplastic starch blends
In this work, the processing and properties of blown films prepared from thermoplastic corn starch (TPS) and polycaprolactone (PCL) were studied, in particular at high TPS content. The influence of processing parameters and material moisture content on the tensile properties was also studied. The re...
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Published in: | Journal of applied polymer science 2012-01, Vol.123 (1), p.179-190 |
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container_title | Journal of applied polymer science |
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creator | Ramírez-Arreola, Daniel E. Robledo-Ortiz, Jorge R. Moscoso, Francisco Arellano, Martín Rodrigue, Denis González-Núñez, Rubén |
description | In this work, the processing and properties of blown films prepared from thermoplastic corn starch (TPS) and polycaprolactone (PCL) were studied, in particular at high TPS content. The influence of processing parameters and material moisture content on the tensile properties was also studied. The results show that final film properties are mainly controlled by the draw ratio, blow‐up ratio and PCL concentration in the blends. The results also show that PCL/TPS films are less hydrophilic as PCL content increases. Finally, it was found that a very narrow processing window exists for this blend. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011. |
doi_str_mv | 10.1002/app.34444 |
format | article |
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J Appl Polym Sci, 2011.</description><subject>Applied sciences</subject><subject>Blends</subject><subject>Controllers</subject><subject>Exact sciences and technology</subject><subject>Machinery and processing</subject><subject>Materials science</subject><subject>mechanical properties</subject><subject>Miscellaneous</subject><subject>Moisture content</subject><subject>morphology</subject><subject>Moulding</subject><subject>Plastics</subject><subject>Polycaprolactone</subject><subject>Polymer blends</subject><subject>Polymer industry, paints, wood</subject><subject>Polymers</subject><subject>Programmable logic devices</subject><subject>Starches</subject><subject>Technology of polymers</subject><subject>Thermoplastic resins</subject><issn>0021-8995</issn><issn>1097-4628</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNp1kE9r3DAQxUVpodttD_0GhlJoD85qLOuPjyE0m0BIQwjkKMbaEVGqtV3JS7vfvtpukkOhcxmY-b3H4zH2EfgJcN6scJpORFvmFVsA73Tdqsa8Zovyg9p0nXzL3uX8yDmA5GrBbs9D3FZTGh3ljH2IYd5XOGwOp4nSHChXo6-mMe4dlltEN48DreYHSttxipjn4Ko8Y3IPVR9p2OT37I3HmOnD016yu_Nvd2cX9dX39eXZ6VXtRGfaetN67qXxtNGyB_DUEErfKuidErpTXCvZqr7jrjccnebGOE9otNEcGi-W7MvRtqT6uaM8223IjmLEgcZdtqA0iFYL0xT00z_o47hLQwlnQYLqhIYCLtnXI-XSmHMib6cUtpj2Frg9lGtLufZvuYX9_OSI2WH0CQcX8ougkRK0VgdudeR-hUj7_xva05ubZ-f6qAh5pt8vCkw_rNJCS3t_vbZG3cp7cX1h1-IPQUaXzQ</recordid><startdate>20120105</startdate><enddate>20120105</enddate><creator>Ramírez-Arreola, Daniel E.</creator><creator>Robledo-Ortiz, Jorge R.</creator><creator>Moscoso, Francisco</creator><creator>Arellano, Martín</creator><creator>Rodrigue, Denis</creator><creator>González-Núñez, Rubén</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20120105</creationdate><title>Film processability and properties of polycaprolactone/thermoplastic starch blends</title><author>Ramírez-Arreola, Daniel E. ; Robledo-Ortiz, Jorge R. ; Moscoso, Francisco ; Arellano, Martín ; Rodrigue, Denis ; González-Núñez, Rubén</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3984-d4f0f58fed75b11fe2ea5f461bc63796076546b90cb80ac7088cfea8787012f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Applied sciences</topic><topic>Blends</topic><topic>Controllers</topic><topic>Exact sciences and technology</topic><topic>Machinery and processing</topic><topic>Materials science</topic><topic>mechanical properties</topic><topic>Miscellaneous</topic><topic>Moisture content</topic><topic>morphology</topic><topic>Moulding</topic><topic>Plastics</topic><topic>Polycaprolactone</topic><topic>Polymer blends</topic><topic>Polymer industry, paints, wood</topic><topic>Polymers</topic><topic>Programmable logic devices</topic><topic>Starches</topic><topic>Technology of polymers</topic><topic>Thermoplastic resins</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ramírez-Arreola, Daniel E.</creatorcontrib><creatorcontrib>Robledo-Ortiz, Jorge R.</creatorcontrib><creatorcontrib>Moscoso, Francisco</creatorcontrib><creatorcontrib>Arellano, Martín</creatorcontrib><creatorcontrib>Rodrigue, Denis</creatorcontrib><creatorcontrib>González-Núñez, Rubén</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ramírez-Arreola, Daniel E.</au><au>Robledo-Ortiz, Jorge R.</au><au>Moscoso, Francisco</au><au>Arellano, Martín</au><au>Rodrigue, Denis</au><au>González-Núñez, Rubén</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Film processability and properties of polycaprolactone/thermoplastic starch blends</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2012-01-05</date><risdate>2012</risdate><volume>123</volume><issue>1</issue><spage>179</spage><epage>190</epage><pages>179-190</pages><issn>0021-8995</issn><issn>1097-4628</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>In this work, the processing and properties of blown films prepared from thermoplastic corn starch (TPS) and polycaprolactone (PCL) were studied, in particular at high TPS content. The influence of processing parameters and material moisture content on the tensile properties was also studied. The results show that final film properties are mainly controlled by the draw ratio, blow‐up ratio and PCL concentration in the blends. The results also show that PCL/TPS films are less hydrophilic as PCL content increases. Finally, it was found that a very narrow processing window exists for this blend. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011.</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.34444</doi><tpages>12</tpages></addata></record> |
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subjects | Applied sciences Blends Controllers Exact sciences and technology Machinery and processing Materials science mechanical properties Miscellaneous Moisture content morphology Moulding Plastics Polycaprolactone Polymer blends Polymer industry, paints, wood Polymers Programmable logic devices Starches Technology of polymers Thermoplastic resins |
title | Film processability and properties of polycaprolactone/thermoplastic starch blends |
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