Syntheses, Structures, and Luminescent Properties of Two Novel Coordination Polymers with Mixed Ligands

• Published in: Journal of inorganic and organometallic polymers and materials 2012-03, Vol.22 (2), p.395-403
• Main Authors: Yan, Li, Li, Chuan-Bi, Zhu, Dong-Sheng, Xu, Lin
• Format: Article
• Language: English
• Subjects: Chemistry; Chemistry and Materials Science; Coordination polymers; Crystallization; Diffraction; Hydrogen bonds; Inorganic Chemistry; Ligands; Metal ions; Nitrogen atoms; Organic Chemistry; Organometallic polymers; Polymer Sciences
• ISSN: 1574-1443; 1574-1451
• DOI: 10.1007/s10904-011-9591-6

Two novel metal–organic coordination polymers {[Pb 2 (MIP) 2 (BDC) 2 ]·H 2 O} n 1 and [Cd(MIP)(NDC)] n 2 [MIP = 2-(3-methoxyphenyl)-1H-imidazo [4,5-f] [1, 10] phenanthroline, BDC = terephthalic acid, NDC = naphthalene-1,4-dicarboxylic acid] were obtained from hydrothermal reaction and characterized by elemental analysis, thermogravimetric (TG) analysis, infrared spectrum (IR) and single-crystal X-ray diffraction. The coordination polymers crystallize in triclinic, space group P -1 with a  = 1.0335(2), b  = 1.4224(3), c  = 1.8156(4) nm, β  = 106.088(3)° for complex 1 and the complex 2 crystallizes in monoclinic, space group P 2(1)/ n with a  = 1.2562(8), b  = 1.4800(9), c  = 1.3723(8) nm, β  = 97.257(1)°, respectively. The metal ions Pb(II) are located in [:PbN2O4] pentagonal bipyramidal geometry in complex 1 . The metal ions Cd(II) in complex 2 act as distorted octahedral geometry, being surrounded by four carboxylate oxygen atoms from three NDC ligands and two donor nitrogen atoms from one MIP molecule. Moreover, there are hydrogen bonds in the two complexes, and it is noteworthy that the existence of hydrogen bonds and π–π interactions reinforce the structural stability of the title complexes, which have been proved by TG analysis. The luminescent properties for the ligand MIP, NDC and complex 2 are also discussed in detail.