Investigation of long-term engine oil performance using lab-based artificial ageing illustrated by the impact of ethanol as fuel component

• Published in: Tribology international 2012-02, Vol.46 (1), p.174-182
• Main Authors: Besser, Charlotte, Schneidhofer, Christoph, Dörr, Nicole, Novotny-Farkas, Franz, Allmaier, Günter
• Format: Article
• Language: English
• Subjects: Acetaldehyde; Acetic acid; Aging; Applied sciences; Automotive engines; Chemical degradation; Condition monitoring; Crashworthiness; Ethanol; Ethyl alcohol; Exact sciences and technology; Friction, wear, lubrication; Impact strength; Industrial metrology. Testing; Lubrication oil; Machine components; Mechanical engineering. Machine design; Oxidative degradation
• ISSN: 0301-679X; 1879-2464
• DOI: 10.1016/j.triboint.2011.06.026

The effect of ethanol and its combustion products on the lubrication system is not very well understood. In this paper, a novel lab-based artificial ageing method for the evaluation of engine oils for bio-fuelled automotives and the results thereof are presented. Artificial ageing of three fully formulated engine oils with addition of ethanol, acetaldehyde, and acetic acid was carried out. The oil formulations chosen represent a consequent series of optimisation steps based on the engine oil performance in terms of preservation of typical oil parameters, e.g. base reserve and oxidation, observed during the artificial ageing procedure. It was shown that ethanol as well as acetaldehyde has almost no effect on the oil degradation especially in the case that advanced additive technology was used. On the contrary, acetic acid significantly affected the formulated oil showing influence on the detergent chemistry and even caused sludge formation. The use of the novel artificial ageing method proved to clearly differentiate the impact of the respective compounds added with the possibility to simulate enhanced stress conditions without the need of time-consuming and expensive engine bench tests. Hence, the novel setup offers valuable input for the formulation and the pre-selection of future engine oils suitable for bio-fuel. ► Lab-based artificial ageing for close-to-reality ageing of oils. ► Understanding of ageing mechanisms due to interaction with bio-components. ► Valuable input for the development of novel engine oil formulations. ► Clear differentiation of impact of oxygenated fuel compounds on engine oil stability. ► Evaluation of long-term effectiveness of engine oils for these special application.