New monomers and polymers via Diels-Alder cycloaddition

The series of new bis(naphthalic anhydrides) was prepared through Diels‐Alder cycloaddition. The Diels‐Alder cycloaddition was used as a synthetic route to new phenylated monomers as well as to polymers. All polymers synthesized revealed to be soluble in a wide range of organic solvents such as tolu...

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Bibliographic Details
Published in:Macromolecular symposia. 2003-10, Vol.199 (1), p.97-108
Main Authors: Rusanov, Alexander L., Shifrina, Zinaida B., Bulycheva, Elena G., Keshtov, Mukhamed L., Averina, Marina S., Fogel, Yulia I., Muellen, Klaus, Harris, Frank W.
Format: Article
Language:English
Subjects:
Anhydrides
Chloroform
Cycloaddition
Diels-Alder polymers
Electrooptical
gel-permeation chromatography
isomers
Monomers
phenylated polyphenylenes
Polymers
Solvents
synthesis
Toluene
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Summary:The series of new bis(naphthalic anhydrides) was prepared through Diels‐Alder cycloaddition. The Diels‐Alder cycloaddition was used as a synthetic route to new phenylated monomers as well as to polymers. All polymers synthesized revealed to be soluble in a wide range of organic solvents such as toluene, THF, chloroform, and displayed high thermostability. Therefore, they can be processed easily and are promising candidates for advanced coating systems as well as for electrooptical applications.
ISSN:1022-1360
1521-3900
DOI:10.1002/masy.200350909