Effect of gamma-irradiation on the mechanical properties of polyacrylonitrile-based carbon fiber

• Published in: Carbon (New York) 2013-02, Vol.52, p.427-439
• Main Authors: Xiao, Hao, Lu, Yonggen, Wang, Mouhua, Qin, Xianying, Zhao, Weizhe, Luan, Jian
• Format: Article
• Language: English
• Subjects: Carbon fiber reinforced plastics; Condensed matter: structure, mechanical and thermal properties; Cross-disciplinary physics: materials science; rheology; Crosslinking; Exact sciences and technology; Fibers; Fullerenes and related materials; diamonds, graphite; Graphene; Irradiation; Materials science; Mechanical and acoustical properties of condensed matter; Mechanical properties; Physical radiation effects, radiation damage; Physics; Specific materials; Structure of solids and liquids; crystallography; Tensile strength; γ ray effects
• ISSN: 0008-6223; 1873-3891
• DOI: 10.1016/j.carbon.2012.09.054

The influence of gamma-irradiation on the structure and mechanical properties of polyacrylonitrile-based carbon fibers was studied. It was observed that the Young’s modulus of the fibers irradiated increased with irradiation dose, increasing to 267GPa at 300kGy, a 16.1% improvement compared to that of as-received carbon fiber. However, the tensile strength increased to 5.4GPa at 30kGy, i.e., a 17.4% increase, and then dropped to 4.65GPa at 300kGy, which is almost the same as for the untreated fiber. Uniform stress model analysis and Raman spectroscopy show that the degree of covalent cross-linking between the graphene planes increased to a maximum at 30kGy and then remained almost constant with further irradiation. The SEM images show that the degree of surface roughness increased with the increasing irradiation dose. It is believed that when the dose is less than 30kGy, the increased cross-linking is the dominant effect, and thus improves the tensile strength. On the other hand, further irradiation generates surface flaws, which neutralizes the increase and results in a decrease of tensile strength.