Preferential CO oxidation in H sub(2)-rich stream over Au/CeO sub(2) catalysts prepared via modified deposition-precipitation

• Published in: Journal of industrial and engineering chemistry (Seoul, Korea) Korea), 2011-07, Vol.17 (4), p.747-754
• Main Authors: Sakwarathorn, Theerathad, Luengnaruemitchai, Apanee, Pongstabodee, Sangobtip
• Format: Article
• Language: English
• Subjects: Carbon dioxide; Carbon monoxide; Catalysis; Catalysts; Formates; Gold; Nanostructure; Oxidation
• ISSN: 1226-086X
• DOI: 10.1016/j.jiec.2011.05.032

Preferential CO oxidation in a H sub(2)-rich stream over Au/CeO sub(2) catalysts prepared via modified deposition-precipitation by using different precipitating agents at various pH values was investigated in this research work. The prepared catalysts were characterized by XRD, TEM, XRF, BET, TPR, UV-vis, and FTIR. The experimental results showed that the Au/CeO sub(2) catalysts prepared by using NaOH as a precipitating agent at pH 7 expressed the highest catalytic activities (complete conversion and 51% selectivity at 40 degree C) due to its well-dispersed nano-size Au particles on the support surface with narrower particle size distribution. When adding CO sub(2) to the feed stream, the catalytic performance was decreased dramatically due to the formation of the formate species. The co-addition of CO sub(2) and H sub(2)O in the feedstream had a less negative effect on the CO oxidation compared to the effect of CO sub(2) alone. Water can attack and decompose the carbonate intermediate; the accumulation of the formate species on the active sites of the catalysts is then decreased and the catalytic performance is improved. After in situ thermal regeneration under 5% oxygen in helium at 110 degree C for 2 h, more active sites for the preferential CO oxidation reaction were recovered since the oxygen reacted with the formate species to form CO sub(2). In addition, the Au/CeO sub(2) catalysts exhibited good stability during the tested time in this study.