The structure and spectroscopic characterization of complexes with tetraethyl methylenediphosphonate in solution and in solid state

The crystal structure of UO 2 2 + complex with tetraethyl methylenediphosphonate, CH2[P(O)(OCH2CH3)2]2, POPO, and its spectroscopic characterization in solution and in solid state are discussed. The complex was also characterized by CHN microanalytical procedures, infrared, absorption and luminescen...

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Bibliographic Details
Published in:Journal of molecular structure 2012-03, Vol.1011, p.145-148
Main Authors: Piskuła, Z., Manszewski, T., Kubicki, M., Lis, S.
Format: Article
Language:English
Subjects:
Crystal structure
Diffraction
Infrared
Luminescence
Molecular structure
Solid state
Spectroscopy
X-rays
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Summary:The crystal structure of UO 2 2 + complex with tetraethyl methylenediphosphonate, CH2[P(O)(OCH2CH3)2]2, POPO, and its spectroscopic characterization in solution and in solid state are discussed. The complex was also characterized by CHN microanalytical procedures, infrared, absorption and luminescence spectroscopy and by single crystal X-ray diffraction. Uranyl in the [UO2(POPO)(NO3)2] complex is six-coordinated.
ISSN:0022-2860
DOI:10.1016/j.molstruc.2011.12.054