Using a flow-batch analyzer for photometric determination of Fe( iii ) in edible and lubricating oils without external pretreatment

In this study a flow-batch analyzer (FBA) was utilized and its feasibility was demonstrated for the determination of Fe(iii) in edible and lubricating oils without external pretreatment. The FBA method uses the reaction of this ion with thiocyanate in organic medium. The formed red complex was monit...

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Bibliographic Details
Published in:Analytical methods 2013-01, Vol.5 (4), p.1040-1045
Main Authors: Barreto, Inakã S., Lima, Marcelo B., Andrade, Stéfani Iury E., Araújo, Mário César U., Almeida, Luciano F.
Format: Article
Language:English
Subjects:
Confidence intervals
Edible
Light-emitting diodes
Lubricating oils
Mathematical analysis
Matrices
Matrix methods
Pretreatment
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Summary:In this study a flow-batch analyzer (FBA) was utilized and its feasibility was demonstrated for the determination of Fe(iii) in edible and lubricating oils without external pretreatment. The FBA method uses the reaction of this ion with thiocyanate in organic medium. The formed red complex was monitored by employing a light emitting diode (LED, lambda sub(max) = 520 nm) and a phototransistor linked to the mixing chamber by optical fibers. All standard solutions were prepared in-line and all analytical processes were carried out by simply changing the operational parameters in FBA control software. Comparing with the reference method, no statistically significant differences were observed when applying the paired t-test at a 95% confidence level. The relative standard deviation, analytical frequency and limit of detection were estimated for both viscous matrices (edible and lubricating oils) at
ISSN:1759-9660
1759-9679
DOI:10.1039/C2AY25866H