Nitrided ITQ-2 as an efficient Knoevenagel condensation catalyst

The nitrogen-substituted delaminated ITQ-2 zeolite was found to be a highly active and recyclable catalyst for the Knoevenagel condensation of bulky aromatic aldehydes with ethyl cyanoacetate which cannot take place over the base sites placed within the micropores of conventional zeolites due to spa...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (11), p.1115-1117
Main Authors: Min, Hyung-Ki, Cha, Seung Hyeok, Hong, Suk Bong
Format: Article
Language:English
Subjects:
Aldehydes
Catalysts
Condensing
Delaminating
Zeolites
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Summary:The nitrogen-substituted delaminated ITQ-2 zeolite was found to be a highly active and recyclable catalyst for the Knoevenagel condensation of bulky aromatic aldehydes with ethyl cyanoacetate which cannot take place over the base sites placed within the micropores of conventional zeolites due to spatial limitations.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc38031e