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Determination of standard molar enthalpies of formation of SrMoO₄ micro/nano structures

SrMoO₄ micro/nano structures were prepared by a simple reverse microemulsion method and were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and scanning electron microscope (SEM). In order to associate standard molar enthalpies of formation of nano SrMoO₄ with bulk...

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Bibliographic Details
Published in:Thermochimica acta 2012-02, Vol.530, p.116-119
Main Authors: Guo, Yunxiao, Fan, Gaochao, Huang, Zaiyin, Sun, Jilong, Wang, Lude, Wang, Tenghui, Chen, Jie
Format: Article
Language:English
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Summary:SrMoO₄ micro/nano structures were prepared by a simple reverse microemulsion method and were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and scanning electron microscope (SEM). In order to associate standard molar enthalpies of formation of nano SrMoO₄ with bulk SrMoO₄, the relationship of them was obtained through designing a thermochemical cycle according to thermodynamic potential function method. Combined with microcalorimetry, the standard molar enthalpies of formation of the synthesized micro/nano SrMoO₄ at 298.15K were gained in this paper. And the variation of standard molar enthalpies of formation of micro/nano SrMoO₄ with different morphologies and sizes was discussed.
ISSN:0040-6031
1872-762X
DOI:10.1016/j.tca.2011.12.013