Pyro and Kinetic Studies of Barium Oxalate Crystals Grown in Agar Gel

Single crystals of barium oxalate have been grown using gel method at ambient temperature. Thermal characteristics and kinetic parameters of barium oxalate crystals were determined by thermo-gravimetric (TG) analysis under non-isothermal heating conditions. The pyrolysis experiments were performed w...

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Bibliographic Details
Published in:Journal of crystallization process and technology 2012-10, Vol.2 (4), p.156-160
Main Authors: Dalal, Paresh V., Saraf, Kishor B., Shimpi, Navinchandra G., Shah, Navneet R.
Format: Article
Language:English
Subjects:
Activation energy
Ambient temperature
Crystallization
Crystals
Heating
Heating rate
Oxalates
Pyrolysis
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Summary:Single crystals of barium oxalate have been grown using gel method at ambient temperature. Thermal characteristics and kinetic parameters of barium oxalate crystals were determined by thermo-gravimetric (TG) analysis under non-isothermal heating conditions. The pyrolysis experiments were performed with increasing temperature up-to 600 at heating rate of 5, 7 and 10 in nitrogen gas atmosphere. The pyrolysis curve showed that loss of mass took place mainly in the range of 220 - 400. At higher temperature there was a significant mass loss due to decomposition of oxalates. Ozawa and Coats & Redfern methods were used to determine the apparent activation energies of material degradation. The apparent activation energies for barium oxalate crystals were obtained 187.42 KJ.mol super(-1) and 185.4 KJ.mol super(-1) for the respective methods.
ISSN:2161-7678
2161-7686
DOI:10.4236/jcpt.2012.24023