Dimethyl ether, diethyl ether & ethylene from alcohols over tungstophosphoric acid based mesoporous catalysts

Tungstophosphoric acid (TPA) incorporated silicate structured new mesoporous catalysts were synthesized following one-pot hydrothermal and impregnation procedures. Surface area of TPA@MCM-41, which was prepared by impregnating TPA into MCM-41, was two orders of magnitude higher than the surface area...

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Bibliographic Details
Published in:Chemical engineering journal (1996) 2012-10, Vol.207, p.85-93
Main Authors: Ciftci, Aysegul, Varisli, Dilek, Cem Tokay, Kenan, Aslı Sezgi, N, Dogu, Timur
Format: Article
Language:English
Subjects:
Alcohols
Applied sciences
Catalysis
Catalysts
Catalytic reactions
Chemical engineering
Chemistry
Dehydration
Ethanol
Ethyl alcohol
Ethylene
Exact sciences and technology
General and physical chemistry
methanol
Methyl alcohol
phosphotungstic acid
Reactors
space and time
surface area
temperature
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
washing
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Summary:Tungstophosphoric acid (TPA) incorporated silicate structured new mesoporous catalysts were synthesized following one-pot hydrothermal and impregnation procedures. Surface area of TPA@MCM-41, which was prepared by impregnating TPA into MCM-41, was two orders of magnitude higher than the surface area of pure TPA and this catalyst showed very high activity in dehydration reactions of both ethanol and methanol. Ethanol fractional conversion values reaching to 1.0 was obtained at 300°C at a space time of 0.27s.g/cm³, over TPA@MCM-41. Diethyl ether selectivity showed a decreasing trend by increasing temperature from 180 to 400°C in ethanol dehydration reaction. Ethylene yield values approaching to 100% were obtained at temperatures over 250°C. DME yield passed through a maximum at about 200°C with this catalyst, over which coke formation caused catalyst deactivation. One-pot hydrothermal synthesis procedure was very successful to synthesize a catalyst (TRC-W40) which did not lose any activity after repeated washing steps. This catalyst gave highly stable catalytic performance in dehydration of both ethanol and methanol. Well dispersed WOₓ clusters were formed within the mesoporous silicate matrix of this material. This catalyst showed very good activity in dehydration reactions of alcohols, giving 100% conversion in ethanol dehydration at 400°C and 100% DME selectivity in methanol dehydration at temperatures less than 300°C.
ISSN:1385-8947
1873-3212
DOI:10.1016/j.cej.2012.04.016