A facile "click" approach to functionalised metallosupramolecular architectures

Herein we describe a CuAAC "click" methodology for exo-functionalisation of Pd2L4 metallosupramolecular architectures. The potentially coordinating 1,2,3-triazole does not affect formation of the desired discrete complexes, nor does this external functional decoration affect the cisplatin-...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (33), p.3398-3400
Main Authors: Lewis, James E M, McAdam, C John, Gardiner, Michael G, Crowley, James D
Format: Article
Language:English
Subjects:
Architecture
Assembly
Decoration
Holes
Methodology
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Summary:Herein we describe a CuAAC "click" methodology for exo-functionalisation of Pd2L4 metallosupramolecular architectures. The potentially coordinating 1,2,3-triazole does not affect formation of the desired discrete complexes, nor does this external functional decoration affect the cisplatin-binding ability of the interior cavity of the assembly.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc41209a