Base promoted highly efficient copper fluorapatite catalyzed coupling of phenols with arylboronic acids under mild and ligand-free conditions

A mild, general and highly efficient protocol has been developed for the synthesis of diaryl ethers in good to excellent yield under mild and ligand-free conditions. This is the first example in which a recyclable, heterogeneous copper fluorapatite catalyst is used for the arylation of phenols with...

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Published in:RSC advances 2012-01, Vol.2 (33), p.12818-12823
Main Authors: Mulla, Shafeek A. R., Inamdar, Suleman M., Pathan, Mohsinkhan Y., Chavan, Santosh S.
Format: Article
Language:English
Subjects:
Catalysts
Copper
Fluorapatite
Joining
Methyl alcohol
Phenols
Solvents
Synthesis
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description A mild, general and highly efficient protocol has been developed for the synthesis of diaryl ethers in good to excellent yield under mild and ligand-free conditions. This is the first example in which a recyclable, heterogeneous copper fluorapatite catalyst is used for the arylation of phenols with arylboronic acids at room temperature in the presence of Cs sub(2)CO sub(3) as a base and methanol as a solvent. The catalyst was recovered and reused several times without loss of catalytic activity.
doi_str_mv 10.1039/c2ra21850j
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source Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)
subjects Catalysts
Copper
Fluorapatite
Joining
Methyl alcohol
Phenols
Solvents
Synthesis
title Base promoted highly efficient copper fluorapatite catalyzed coupling of phenols with arylboronic acids under mild and ligand-free conditions
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